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- W1945723501 abstract "Abstract The absorption of linearly polarized infrared radiation by oriented samples is sensitive to the state of polarization of the incident radiation. This phenomenon is known as the infrared linear dichroism (IRLD). The degree of optical anisotropy in oriented samples can be characterized by measuring two spectra using light polarized parallel and perpendicular to a reference direction. In this chapter, the theoretical expressions allowing the quantitative determination of molecular orientation from IRLD measurements for systems showing both uniaxial and biaxial symmetry of orientation are described. In addition, typical examples of the use of IRLD to determine the orientation of polymers are presented. These results were obtained from either static measurements or dynamic measurements using a rotating polarizer, a photoelastic modulator (PM‐IRLD) or ultrarapid scanning‐Fourier transform infrared (URS‐FTIR). The use of these techniques allows one to follow the kinetics of orientation over different timescales down to 40 min." @default.
- W1945723501 created "2016-06-24" @default.
- W1945723501 creator A5029712266 @default.
- W1945723501 creator A5071601782 @default.
- W1945723501 date "2001-12-20" @default.
- W1945723501 modified "2023-10-03" @default.
- W1945723501 title "Infrared Linear Dichroism of Polymers" @default.
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- W1945723501 doi "https://doi.org/10.1002/9780470027325.s8918" @default.
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