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- W1945968644 abstract "A novel method for constructing supramolecular hybrids composed of polyoxometalates and photofunctional metal complexes was developed. A Ru(II) complex with phosphonate groups (RuP) strongly interacted with Zn(II) to afford a 2 : 1 trinuclear metal complex ([(RuP)2Zn](3+)). In dimethylsulfoxide, [(RuP)2Zn](3+) strongly interacted with a Keggin-type heteropolyoxometalate (Si-WPOM) to form a 1 : 1 hybrid ([(RuP)2Zn]-POM). Irradiation of [(RuP)2Zn]-POM in the presence of diethanolamine caused rapid accumulation of the one-electron reduced hybrid with a quantum yield of 0.99." @default.
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- W1945968644 date "2015-01-01" @default.
- W1945968644 modified "2023-10-17" @default.
- W1945968644 title "Synthesis and strong photooxidation power of a supramolecular hybrid comprising a polyoxometalate and Ru(<scp>ii</scp>) polypyridyl complex with zinc(<scp>ii</scp>)" @default.
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- W1945968644 doi "https://doi.org/10.1039/c5fd00080g" @default.
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