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• W1946339838 abstract "A new three-dimensional europium-doped yttrium 1,3,5-benzenetricarboxylate has been obtained under hydrothermal conditions. The structure of MIL-78(Y, Eu) or Y1−xEux((C6H3)–(CO2)3) (x ∼ 0.024) has been solved from X-ray powder diffraction data (a = 6.941(1) Å, b = 14.700(2) Å, c = 8.488(1) Å, β = 107.73(1)°, V = 824.9(4) Å3, space group C2/m (no. 12)). Its structure is built up from chains of edged-sharing eight-coordinated monocapped square antiprism polyhedra and trimesate anions, creating a three-dimensional structure. The same structure is formed by replacing yttrium by a rare-earth element. The thermal behaviour of MIL-78(Y, Eu) has been investigated using TGA and X-ray thermodiffractometry and indicates that MIL-78(Y, Eu) is stable up to 450 °C. The study of the optical properties of samples doped with different rare-earths reveals strong fluorescence under VUV radiation." @default.
• W1946339838 created "2016-06-24" @default.
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• W1946339838 date "2004-01-01" @default.
• W1946339838 modified "2023-10-17" @default.
• W1946339838 title "Synthesis, characterisation and luminescent properties of a new three-dimensional lanthanide trimesate: M((C₆H₃)–(CO₂)₃) (M = Y, Ln) or MIL-78" @default.
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• W1946339838 doi "https://doi.org/10.1039/b312425h" @default.
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