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- W1946393914 startingPage "1869" @default.
- W1946393914 abstract "The electron spin resonance of Mn 2+ impurity ions in natural crystals of morinite, Ca 4 Na 2 Al 4 (F, OH) 10 (PO 4 ) 4∙ 3H 2 O, was studied in the 9.4 GHz microwave frequency range and at room temperature. A single magnetic complex was found and the resonance lines were characterized by strong splittings due to superhyperfine interactions with ligand nuclei. The resonance lines were fitted to a spin Hamiltonian of orthorhombic symmetry and the following parameters were determined: g z = 2.0014 ± 0.0005, g y = 2.0017 ± 0.0010, b 2 °= 166.8 ± 1.5, b 2 2 = 69.1 ± 1.5, b 4 0 = −0.17 ± 0.10, A = 98.2 ± 1.0, and B = C = 99.7 ± 1.5. The values of b n m , A, B, and C are in gauss, and the signs are relative. By heat-treating powdered samples of morinite to a temperature greater than 400 °C, it was shown that the morinite changed to apatite, 2[Ca 5 (PO 4 ) 3 (F, OH)]." @default.
- W1946393914 created "2016-06-24" @default.
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- W1946393914 date "1969-09-01" @default.
- W1946393914 modified "2023-09-24" @default.
- W1946393914 title "Electron spin resonance of Mn2+ impurities in morinite" @default.
- W1946393914 cites W1607286065 @default.
- W1946393914 doi "https://doi.org/10.1139/p69-234" @default.
- W1946393914 hasPublicationYear "1969" @default.
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