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- W1946454741 abstract "Hoveyda–Grubbs type catalysts with cationic tags on NHC ligands were linker-free immobilized on the surface of lamellar zeolitic supports (MCM-22, MCM-56, MCM-36) and on mesoporous molecular sieves SBA-15. The activity of prepared hybrid catalysts was tested in olefin metathesis reactions: the activity in ring-closing metathesis of citronellene and N , N -diallyltrifluoroacetamide decreased in the order of support MCM-22 ≈ MCM-56 > SBA-15 > MCM-36; the hybrid catalyst based on SBA-15 was found the most active in self-metathesis of methyl oleate. All catalysts were reusable and exhibited low Ru leaching (<1% of Ru content). XPS analysis revealed that during immobilization ion exchange between Hoveyda–Grubbs type catalyst and zeolitic support occurred in the case of Cl − counter anion; in contrast, PF 6 − counter anion underwent partial decomposition." @default.
- W1946454741 created "2016-06-24" @default.
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- W1946454741 date "2015-11-04" @default.
- W1946454741 modified "2023-10-17" @default.
- W1946454741 title "Ru complexes of Hoveyda–Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions" @default.
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- W1946454741 doi "https://doi.org/10.3762/bjoc.11.225" @default.
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