FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1946831239> ?p ?o ?g. }

• W1946831239 abstract "(1; R = Me)[18871-66-4] C6H15NO2 (MW 133.19)InChI = 1S/C6H15NO2/c1-6(8-4,9-5)7(2)3/h1-5H3InChIKey = FBZVZUSVGKOWHG-UHFFFAOYSA-N(2; R = Me)[867-89-0] C5H11NO (MW 101.15)InChI = 1S/C5H11NO/c1-5(7-4)6(2)3/h1H2,2-4H3InChIKey = JTZFZDSUVLTEHV-UHFFFAOYSA-N(3; R = Et)[19429-85-7] C8H19NO2 (MW 161.24)InChI = 1S/C8H19NO2/c1-6-10-8(3,9(4)5)11-7-2/h6-7H2,1-5H3InChIKey = XUFDMPZZAIRCGV-UHFFFAOYSA-N(4; R = Et)[816-65-9] C6H13NO (MW 115.17)InChI = 1S/C6H13NO/c1-5-8-6(2)7(3)4/h2,5H2,1,3-4H3InChIKey = BQGJNCWENLLBSP-UHFFFAOYSA-N(Eschenmoser–Claisen rearrangements;2 monoacylation of diols;3 triazine synthesis4)Physical Data: mixture of (1) and (2) bp 105–110 °C; d 0.911 g cm−3. Mixture of (3) and (4) bp 126–129 °C. (2) bp 104–105 °C. (4) bp 126 °C.Solubility: sol benzene, toluene, xylene, DMF, chloroform.Form Supplied in: amide acetal (1) is commercially available, usually as a mixture of (1) and (2). The commercial mixture is 85–95% pure; methanol (5–10%) may be present as a stabilizer.Preparative Method: O-methylation of N,N-dimethylacetamide with Dimethyl Sulfate (or diethyl sulfate), followed by reaction with Sodium Methoxide (or ethoxide). Fractional distillation affords mixtures of (1) and (2) (or 3 and 4). Treatment with calcium metal and redistillation gives the ketene O,N-acetals (2) (58%) (or 4; 74%).5" @default.
• W1946831239 created "2016-06-24" @default.
• W1946831239 creator A5007167282 @default.
• W1946831239 creator A5018291704 @default.
• W1946831239 creator A5058231514 @default.
• W1946831239 creator A5060945983 @default.
• W1946831239 date "2009-03-15" @default.
• W1946831239 modified "2023-09-26" @default.
• W1946831239 title "N,N-Dimethylacetamide Dimethyl Acetal" @default.
• W1946831239 cites W1554278208 @default.
• W1946831239 cites W1835667852 @default.
• W1946831239 cites W1964074749 @default.
• W1946831239 cites W1968023901 @default.
• W1946831239 cites W1980123294 @default.
• W1946831239 cites W1980901375 @default.
• W1946831239 cites W1981670174 @default.
• W1946831239 cites W1990288476 @default.
• W1946831239 cites W1995043149 @default.
• W1946831239 cites W1999095268 @default.
• W1946831239 cites W2000000884 @default.
• W1946831239 cites W2000416991 @default.
• W1946831239 cites W2005038356 @default.
• W1946831239 cites W2013301345 @default.
• W1946831239 cites W2015663914 @default.
• W1946831239 cites W2017522683 @default.
• W1946831239 cites W2017558944 @default.
• W1946831239 cites W2018056568 @default.
• W1946831239 cites W2018953911 @default.
• W1946831239 cites W2021058993 @default.
• W1946831239 cites W2021649619 @default.
• W1946831239 cites W2022175529 @default.
• W1946831239 cites W2022332500 @default.
• W1946831239 cites W2026655808 @default.
• W1946831239 cites W2030951568 @default.
• W1946831239 cites W2033638279 @default.
• W1946831239 cites W2048439614 @default.
• W1946831239 cites W2051949055 @default.
• W1946831239 cites W2062025630 @default.
• W1946831239 cites W2066443544 @default.
• W1946831239 cites W2072779381 @default.
• W1946831239 cites W2078141729 @default.
• W1946831239 cites W2081158872 @default.
• W1946831239 cites W2100620574 @default.
• W1946831239 cites W2120150541 @default.
• W1946831239 cites W2142489990 @default.
• W1946831239 cites W2149943670 @default.
• W1946831239 cites W2161028333 @default.
• W1946831239 cites W2176922171 @default.
• W1946831239 cites W2344673724 @default.
• W1946831239 cites W2949288001 @default.
• W1946831239 cites W2949362801 @default.
• W1946831239 cites W2949666598 @default.
• W1946831239 cites W2949824768 @default.
• W1946831239 cites W2950922929 @default.
• W1946831239 cites W2951352633 @default.
• W1946831239 cites W2951826637 @default.
• W1946831239 cites W2952240669 @default.
• W1946831239 cites W2952548282 @default.
• W1946831239 cites W2952975006 @default.
• W1946831239 cites W2952989100 @default.
• W1946831239 cites W4247923926 @default.
• W1946831239 cites W2051245435 @default.
• W1946831239 cites W2051715168 @default.
• W1946831239 doi "https://doi.org/10.1002/047084289x.rd293.pub2" @default.
• W1946831239 hasPublicationYear "2009" @default.
• W1946831239 type Work @default.
• W1946831239 sameAs 1946831239 @default.
• W1946831239 citedByCount "0" @default.
• W1946831239 crossrefType "reference-entry" @default.
• W1946831239 hasAuthorship W1946831239A5007167282 @default.
• W1946831239 hasAuthorship W1946831239A5018291704 @default.
• W1946831239 hasAuthorship W1946831239A5058231514 @default.
• W1946831239 hasAuthorship W1946831239A5060945983 @default.
• W1946831239 hasConcept C13965031 @default.
• W1946831239 hasConcept C178790620 @default.
• W1946831239 hasConcept C185592680 @default.
• W1946831239 hasConcept C2777731525 @default.
• W1946831239 hasConcept C2777921878 @default.
• W1946831239 hasConcept C2778142098 @default.
• W1946831239 hasConcept C2779193700 @default.
• W1946831239 hasConcept C2779607525 @default.
• W1946831239 hasConcept C2780471494 @default.
• W1946831239 hasConcept C2781189857 @default.
• W1946831239 hasConceptScore W1946831239C13965031 @default.
• W1946831239 hasConceptScore W1946831239C178790620 @default.
• W1946831239 hasConceptScore W1946831239C185592680 @default.
• W1946831239 hasConceptScore W1946831239C2777731525 @default.
• W1946831239 hasConceptScore W1946831239C2777921878 @default.
• W1946831239 hasConceptScore W1946831239C2778142098 @default.
• W1946831239 hasConceptScore W1946831239C2779193700 @default.
• W1946831239 hasConceptScore W1946831239C2779607525 @default.
• W1946831239 hasConceptScore W1946831239C2780471494 @default.
• W1946831239 hasConceptScore W1946831239C2781189857 @default.
• W1946831239 hasLocation W19468312391 @default.
• W1946831239 hasOpenAccess W1946831239 @default.
• W1946831239 hasPrimaryLocation W19468312391 @default.
• W1946831239 hasRelatedWork W1870881130 @default.
• W1946831239 hasRelatedWork W1871162903 @default.
• W1946831239 hasRelatedWork W1901043922 @default.
• W1946831239 hasRelatedWork W1905432625 @default.

• next