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• W1948656640 endingPage "541" @default.
• W1948656640 startingPage "535" @default.
• W1948656640 abstract "The electronic properties of cationic ferric complexes were investigated in molecular materials and in a negatively charged lamellar host matrix. Two cations, [FeIII(R-Sal2Trien)]+ [where H2-R-Sal2Trien is the hexadentate ligand derived from triethylenetetramine and R-substituted salicylaldehydes (R = 3,5-Cl2 or 5-OMe)], were first assembled with different anions (NO3−, ClO4−, PF6− or BPh4−). The obtained compounds exhibit various magnetic behaviours. S = 5/2 high-spin species, S = 1/2 low-spin species and S = 5/2 ↔ S = 1/2 spin-crossover complexes were identified from variable-temperature SQUID measurements and, in the case of the two cations associated to ClO4− and PF6−, were confirmed by their X-ray crystal structures at 293 K. When the ferric cations are intercalated within the van der Waals gap of the lamellar CdPS3 host phase, their structural and electronic characteristics appear to be strongly affected. The incomplete spin crossover observed for [Fe(5-OMe-Sal2Trien)]0.26Cd0.87PS3˙nH2O and the low-spin behaviour of [Fe(3,5-Cl2-Sal2Trien)]0.22Cd0.89PS3 can be partly attributed to a different arrangement of the cationic species in the interlamellar space." @default.
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• W1948656640 date "2004-01-01" @default.
• W1948656640 modified "2023-10-18" @default.
• W1948656640 title "Structural effects on the magnetic properties of ferric complexes in molecular materials or a lamellar CdPS₃host matrix" @default.
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• W1948656640 doi "https://doi.org/10.1039/b311371j" @default.
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