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- W1949127921 abstract "Abstract Bacteriochlorophyll b (bchl b) has been isolated from the halophilic photosynthetic bacterium, Ectothiorhodospira halochloris. The pigment and a series of derivatives thereof are different from Bchl b from Rhodopseudomonas viriais by HPLC analysis, but similar by uv-vis spectroscopy. The chromatographic difference originates in different esterifying alcohols in the two pigments. The one from Rp. viridis (Bchl b p ) is esterified with ⊿2-phytaenol (phytol), that from E. halochloris (Bchl b ⊿2,10 ) with ⊿2,10-phytadienol. The structure of the latter has been established by isolation of the alcohol from the purified pigment, followed by (i) gaschromatography-mass spectroscopy and (ii) ozonolysis and dinitrophenylhydrazon-formation of the cleavage products, which were identified by gaschromatography-mass spectroscopy as 6-methyl-heptan-2-one, and 4-methyl-nona-1,8-dione." @default.
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- W1949127921 date "1981-06-01" @default.
- W1949127921 modified "2023-10-12" @default.
- W1949127921 title "⊿2,10-Phytadienol as Esterifying Alcohol of Bacteriochlorophyll b from Ectothiorhodospira halochloris" @default.
- W1949127921 doi "https://doi.org/10.1515/znc-1981-5-613" @default.
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