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• W1949238412 endingPage "5272" @default.
• W1949238412 startingPage "5265" @default.
• W1949238412 abstract "The alkyl radical (R1) addition reaction to ortho-X-substituted N-(benzylidene)-2-methylpropane-2-sulfinamides (X = Br, CN, CO2Me, OH and OMe) is highly diastereoselective, regardless of the electronic properties of the X group and the size of R1. Easy removal of the sulfinyl group provides the title compounds in enantiomerically pure form. This two-step sequence has been successfully applied to the preparation of primary α-(tert-butyl)-ortho-hydroxy- and -ortho-methoxybenzylamines, as well as the 3-isopropyl-substituted isoindolin-1-one." @default.
• W1949238412 created "2016-06-24" @default.
• W1949238412 creator A5018567652 @default.
• W1949238412 creator A5031362868 @default.
• W1949238412 creator A5053956461 @default.
• W1949238412 creator A5068627557 @default.
• W1949238412 date "2014-07-11" @default.
• W1949238412 modified "2023-10-18" @default.
• W1949238412 title "Synthesis of Enantiomerically Pure (α-Phenylalkyl)amines with Substituents at the<i>ortho</i>Position through Diastereoselective Radical Alkylation Reaction of Sulfinimines" @default.
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• W1949238412 doi "https://doi.org/10.1002/ejoc.201402355" @default.
• W1949238412 hasPublicationYear "2014" @default.
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