FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1952018733> ?p ?o ?g. }

• W1952018733 abstract "A comprehensive thermodynamic database based on the Helgeson-Kirkham-Flowers (HKF) equation of state was developed for metal complexes in hydrothermal systems. Because this equation of state has been shown to accurately predict standard partial molal thermodynamic properties of aqueous species at elevated temperatures and pressures, this study provides the necessary foundation for future exploration into transport and depositional processes in polymetallic ore deposits. The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver sulfide and hydroxide complexes were derived from experimental equilibrium constants using nonlinear regression calculations. In order to ensure that the resulting parameters were internally consistent, those experiments utilizing incompatible thermodynamic data were re-speciated prior to regression. Because new experimental studies were used to revise the HKF parameters for H2S0 and HS-1, those metal complexes for which HKF parameters had been previously derived were also updated. It was found that predicted thermodynamic properties of metal complexes are consistent with linear correlations between standard partial molal thermodynamic properties. This result allowed assessment of several complexes for which experimental data necessary to perform regression calculations was limited. Oxygen fugacity-temperature diagrams were calculated to illustrate how thermodynamic data improves our understanding of depositional processes. Predicted thermodynamic properties were used to investigate metal transport in Carlin-type gold deposits. Assuming a linear relationship between temperature and pressure, metals are predicted to predominantly be transported as sulfide complexes at a total aqueous sulfur concentration of 0.05 m. Also, the presence of arsenic and antimony mineral phases in the deposits are shown to restrict mineralization within a limited range of chemical conditions. Finally, at a lesser aqueous sulfur concentration of 0.01 m, host rock sulfidation can explain the origin of arsenic and antimony minerals within the paragenetic sequence." @default.
• W1952018733 created "2016-06-24" @default.
• W1952018733 creator A5033130017 @default.
• W1952018733 creator A5072154960 @default.
• W1952018733 date "2003-03-23" @default.
• W1952018733 modified "2023-09-26" @default.
• W1952018733 title "The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver" @default.
• W1952018733 cites W1516461961 @default.
• W1952018733 cites W1588849805 @default.
• W1952018733 cites W1599206114 @default.
• W1952018733 cites W1626708004 @default.
• W1952018733 cites W173946218 @default.
• W1952018733 cites W1862666769 @default.
• W1952018733 cites W1963817594 @default.
• W1952018733 cites W1965920946 @default.
• W1952018733 cites W1967540505 @default.
• W1952018733 cites W1969051824 @default.
• W1952018733 cites W1971379184 @default.
• W1952018733 cites W1976433716 @default.
• W1952018733 cites W1982755393 @default.
• W1952018733 cites W1982952195 @default.
• W1952018733 cites W1988720418 @default.
• W1952018733 cites W1989514260 @default.
• W1952018733 cites W1995217991 @default.
• W1952018733 cites W1997405962 @default.
• W1952018733 cites W1997485275 @default.
• W1952018733 cites W1999549708 @default.
• W1952018733 cites W2004020459 @default.
• W1952018733 cites W2006737361 @default.
• W1952018733 cites W2014365296 @default.
• W1952018733 cites W2030134340 @default.
• W1952018733 cites W2033055837 @default.
• W1952018733 cites W2033878695 @default.
• W1952018733 cites W2042101891 @default.
• W1952018733 cites W2045613961 @default.
• W1952018733 cites W2048419852 @default.
• W1952018733 cites W2053032930 @default.
• W1952018733 cites W2063261643 @default.
• W1952018733 cites W2063606616 @default.
• W1952018733 cites W2065432424 @default.
• W1952018733 cites W2066527077 @default.
• W1952018733 cites W2067719049 @default.
• W1952018733 cites W2069768862 @default.
• W1952018733 cites W2072011665 @default.
• W1952018733 cites W2073403425 @default.
• W1952018733 cites W2079598225 @default.
• W1952018733 cites W2081258920 @default.
• W1952018733 cites W2085415496 @default.
• W1952018733 cites W2087806970 @default.
• W1952018733 cites W2088381358 @default.
• W1952018733 cites W2089490968 @default.
• W1952018733 cites W2091484833 @default.
• W1952018733 cites W2101108033 @default.
• W1952018733 cites W2101525489 @default.
• W1952018733 cites W2108691289 @default.
• W1952018733 cites W2111110876 @default.
• W1952018733 cites W2111473359 @default.
• W1952018733 cites W2135942119 @default.
• W1952018733 cites W2135999306 @default.
• W1952018733 cites W2138226392 @default.
• W1952018733 cites W2144000823 @default.
• W1952018733 cites W2146371856 @default.
• W1952018733 cites W2146467208 @default.
• W1952018733 cites W2158907265 @default.
• W1952018733 cites W2170386347 @default.
• W1952018733 cites W2314502767 @default.
• W1952018733 cites W2315892471 @default.
• W1952018733 cites W2320903144 @default.
• W1952018733 cites W2322700446 @default.
• W1952018733 cites W2326147311 @default.
• W1952018733 cites W2330678088 @default.
• W1952018733 cites W2883184119 @default.
• W1952018733 cites W3116445466 @default.
• W1952018733 cites W2513504789 @default.
• W1952018733 doi "https://doi.org/10.2172/840338" @default.
• W1952018733 hasPublicationYear "2003" @default.
• W1952018733 type Work @default.
• W1952018733 sameAs 1952018733 @default.
• W1952018733 citedByCount "6" @default.
• W1952018733 countsByYear W19520187332012 @default.
• W1952018733 countsByYear W19520187332015 @default.
• W1952018733 countsByYear W19520187332017 @default.
• W1952018733 countsByYear W19520187332018 @default.
• W1952018733 countsByYear W19520187332021 @default.
• W1952018733 crossrefType "report" @default.
• W1952018733 hasAuthorship W1952018733A5033130017 @default.
• W1952018733 hasAuthorship W1952018733A5072154960 @default.
• W1952018733 hasBestOaLocation W19520187333 @default.
• W1952018733 hasConcept C121332964 @default.
• W1952018733 hasConcept C147789679 @default.
• W1952018733 hasConcept C16946580 @default.
• W1952018733 hasConcept C178790620 @default.
• W1952018733 hasConcept C179104552 @default.
• W1952018733 hasConcept C184651966 @default.
• W1952018733 hasConcept C185592680 @default.
• W1952018733 hasConcept C199360897 @default.
• W1952018733 hasConcept C2775896084 @default.
• W1952018733 hasConcept C2777777548 @default.
• W1952018733 hasConcept C2780596425 @default.
• W1952018733 hasConcept C41008148 @default.

• next