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- W1954346062 endingPage "532" @default.
- W1954346062 startingPage "526" @default.
- W1954346062 abstract "The syntheses and structures of heteroleptic germanium(II) and tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene are described. The reaction of ArN=C(Me)C(Me)=NAr (L, Ar = 2,6-iPr2C6H3) with MeLi in Et2O, followed by treatment with GeCl2·dioxane or SnCl2, afforded [L1ECl] [L1 = ArN=C(Me)C(Me)2NAr; E = Ge (1), Sn (2)]. Moreover, L2Li [L2 = ArN=C(Me)C(=CH2)NAr] reacted with GeCl2·dioxane in Et2O to form [{C(=CH)NAr}{C(Me)=NAr}]2(GeCl)2 (3). The byproducts are [{C(CH2)NAr}{C(Me)=NAr}Ge]2 (4) and L2H (5). Furthermore, the reaction of L with LiNiPr2 in Et2O, followed by treatment with SnCl2, afforded [L2SnCl] (6). Compounds 1–4 and 6 have been characterized by NMR spectroscopy and X-ray crystallography." @default.
- W1954346062 created "2016-06-24" @default.
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- W1954346062 date "2013-12-06" @default.
- W1954346062 modified "2023-09-23" @default.
- W1954346062 title "Heteroleptic Germanium(II) and Tin(II) Chlorides Supported by Anionic Ligands Derived from 2,3‐Dimethyl‐1,4‐diaza‐1,3‐butadiene" @default.
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