FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1954565016> ?p ?o ?g. }

• W1954565016 endingPage "533" @default.
• W1954565016 startingPage "523" @default.
• W1954565016 abstract "The homologous series of phenyl and pyridyl substituted bis(acrylamido)alkanes have been synthesized with the aim of systematic analysis of their crystal structures and their solid-state [2 + 2] reactivities. The changes in the crystal structures with respect to a small change in the molecular structure, that is by varying alkyl spacers between acrylamides and/or by varying the end groups (phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl) on the C-terminal of the amide, were analyzed in terms of hydrogen-bonding interference (N-H⋯Npy versus N-H⋯O=C) and network geometries. In this series, a greater tendency towards the formation of N-H⋯O hydrogen bonds (β-sheets and two-dimensional networks) over N-H⋯N hydrogen bonds was observed. Among all the structures seven structures were found to have the required alignments of double bonds for the [2 + 2] reaction such that the formations of single dimer, double dimer and polymer are facilitated. However, only four structures were found to exhibit such a solid-state [2 + 2] reaction to form a single dimer and polymers. The two-dimensional hydrogen-bonding layer via N-H⋯O hydrogen bonds was found to promote solid-state [2 + 2] photo-polymerization in a single-crystal-to-single-crystal manner. Such two-dimensional layers were encountered only when the spacer between acryl amide moieties is butyl. Only four out of the 16 derivatives were found to form hydrates, two each from 2-pyridyl and 4-pyridyl derivatives. The water molecules in these structures govern the hydrogen-bonding networks by the formation of an octameric water cluster and one-dimensional zigzag water chains. The trends in the melting points and densities were also analyzed." @default.
• W1954565016 created "2016-06-24" @default.
• W1954565016 creator A5045246849 @default.
• W1954565016 creator A5090825991 @default.
• W1954565016 date "2015-07-31" @default.
• W1954565016 modified "2023-09-26" @default.
• W1954565016 title "Exploration and exploitation of homologous series of bis(acrylamido)alkanes containing pyridyl and phenyl groups: β-sheet<i>versus</i>two-dimensional layers in solid-state photochemical [2 + 2] reactions" @default.
• W1954565016 cites W1697131041 @default.
• W1954565016 cites W1969360633 @default.
• W1954565016 cites W1972646318 @default.
• W1954565016 cites W1983897909 @default.
• W1954565016 cites W1987918731 @default.
• W1954565016 cites W1991823771 @default.
• W1954565016 cites W1994120546 @default.
• W1954565016 cites W1997380582 @default.
• W1954565016 cites W2000753651 @default.
• W1954565016 cites W2001175141 @default.
• W1954565016 cites W2002077062 @default.
• W1954565016 cites W2003498295 @default.
• W1954565016 cites W2005254092 @default.
• W1954565016 cites W2015079217 @default.
• W1954565016 cites W2027075112 @default.
• W1954565016 cites W2028990075 @default.
• W1954565016 cites W2039331521 @default.
• W1954565016 cites W2047212438 @default.
• W1954565016 cites W2053902000 @default.
• W1954565016 cites W2056603102 @default.
• W1954565016 cites W2057889085 @default.
• W1954565016 cites W2060281648 @default.
• W1954565016 cites W2064742935 @default.
• W1954565016 cites W2073635116 @default.
• W1954565016 cites W2076492590 @default.
• W1954565016 cites W2080869151 @default.
• W1954565016 cites W2080893137 @default.
• W1954565016 cites W2082269735 @default.
• W1954565016 cites W2094317472 @default.
• W1954565016 cites W2098578488 @default.
• W1954565016 cites W2107802815 @default.
• W1954565016 cites W2131214655 @default.
• W1954565016 cites W2143963771 @default.
• W1954565016 cites W2148624934 @default.
• W1954565016 cites W2313306170 @default.
• W1954565016 cites W2329531074 @default.
• W1954565016 cites W2331429038 @default.
• W1954565016 cites W29179573 @default.
• W1954565016 doi "https://doi.org/10.1107/s2052252515009987" @default.
• W1954565016 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4547820" @default.
• W1954565016 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26306194" @default.
• W1954565016 hasPublicationYear "2015" @default.
• W1954565016 type Work @default.
• W1954565016 sameAs 1954565016 @default.
• W1954565016 citedByCount "8" @default.
• W1954565016 countsByYear W19545650162016 @default.
• W1954565016 countsByYear W19545650162017 @default.
• W1954565016 countsByYear W19545650162019 @default.
• W1954565016 crossrefType "journal-article" @default.
• W1954565016 hasAuthorship W1954565016A5045246849 @default.
• W1954565016 hasAuthorship W1954565016A5090825991 @default.
• W1954565016 hasBestOaLocation W19545650161 @default.
• W1954565016 hasConcept C112887158 @default.
• W1954565016 hasConcept C115624301 @default.
• W1954565016 hasConcept C178790620 @default.
• W1954565016 hasConcept C185592680 @default.
• W1954565016 hasConcept C188027245 @default.
• W1954565016 hasConcept C199360897 @default.
• W1954565016 hasConcept C2776482079 @default.
• W1954565016 hasConcept C2778439535 @default.
• W1954565016 hasConcept C2779546866 @default.
• W1954565016 hasConcept C2780263894 @default.
• W1954565016 hasConcept C2781285689 @default.
• W1954565016 hasConcept C32909587 @default.
• W1954565016 hasConcept C41008148 @default.
• W1954565016 hasConcept C8010536 @default.
• W1954565016 hasConceptScore W1954565016C112887158 @default.
• W1954565016 hasConceptScore W1954565016C115624301 @default.
• W1954565016 hasConceptScore W1954565016C178790620 @default.
• W1954565016 hasConceptScore W1954565016C185592680 @default.
• W1954565016 hasConceptScore W1954565016C188027245 @default.
• W1954565016 hasConceptScore W1954565016C199360897 @default.
• W1954565016 hasConceptScore W1954565016C2776482079 @default.
• W1954565016 hasConceptScore W1954565016C2778439535 @default.
• W1954565016 hasConceptScore W1954565016C2779546866 @default.
• W1954565016 hasConceptScore W1954565016C2780263894 @default.
• W1954565016 hasConceptScore W1954565016C2781285689 @default.
• W1954565016 hasConceptScore W1954565016C32909587 @default.
• W1954565016 hasConceptScore W1954565016C41008148 @default.
• W1954565016 hasConceptScore W1954565016C8010536 @default.
• W1954565016 hasIssue "5" @default.
• W1954565016 hasLocation W19545650161 @default.
• W1954565016 hasLocation W19545650162 @default.
• W1954565016 hasLocation W19545650163 @default.
• W1954565016 hasLocation W19545650164 @default.
• W1954565016 hasLocation W19545650165 @default.
• W1954565016 hasOpenAccess W1954565016 @default.
• W1954565016 hasPrimaryLocation W19545650161 @default.
• W1954565016 hasRelatedWork W108162294 @default.
• W1954565016 hasRelatedWork W1991883810 @default.
• W1954565016 hasRelatedWork W2031538813 @default.

• next