Matches in SemOpenAlex for { <https://semopenalex.org/work/W1956942179> ?p ?o ?g. }
- W1956942179 endingPage "1420" @default.
- W1956942179 startingPage "1411" @default.
- W1956942179 abstract "The reactions of CF3O radicals with (1) NO and (2) NO2 were studied using two different experimental techniques. A laser photolysis/LIF detection method was applied for measuring the rate constants as a function of temperature (T = 222–302 K) and total pressure (ptot = 7–107 mbar). Whereas the reaction with (1) NO was found to be independent of temperature and pressure with k1 = (4.5±1.2)×10−11 cm3 s−1, the reaction with (2) NO2 was found to be dependent on both of these variables. The temperature dependence of k2 in the high pressure limit can be given by the expression k2,∝ (T) = (8±5)×10−13 exp ((863±194) K/T) cm3 s−1. The product distributions of the two reactions were determined in separate experiments using steady-state photolysis combined with FTIR spectroscopy. For reaction (1) only CF2O was found as a reaction product with a yield of 0.93±0.10, independent of temperature. For reaction (2) several products (CF3ONO2, CF2O, FNO2) were identified, the overall yield, however, is dominated (≥90%) by the recombination product CF3ONO2. A theoretical analysis of the detailed mechanisms of both reactions was made by performing ab initio energy and geometry predictions in combination with RRKM calculations. Both reactions were found to proceed via an initial addition mechanism involving the CF3ONOx (x = 1, 2) intermediate and a four-center transition state. A direct abstraction of an F atom by NO or NO2 can be excluded." @default.
- W1956942179 created "2016-06-24" @default.
- W1956942179 creator A5001016101 @default.
- W1956942179 creator A5001304596 @default.
- W1956942179 creator A5027004966 @default.
- W1956942179 creator A5049901030 @default.
- W1956942179 date "1997-10-01" @default.
- W1956942179 modified "2023-09-25" @default.
- W1956942179 title "Kinetic and Mechanistic Studies of the Reactions of CF<sub>3</sub>O Radicals with NO and NO<sub>2</sub>" @default.
- W1956942179 cites W142554214 @default.
- W1956942179 cites W1506300717 @default.
- W1956942179 cites W152001490 @default.
- W1956942179 cites W1975999752 @default.
- W1956942179 cites W1977601786 @default.
- W1956942179 cites W1977647447 @default.
- W1956942179 cites W1984315558 @default.
- W1956942179 cites W1991352026 @default.
- W1956942179 cites W1996275350 @default.
- W1956942179 cites W2002247554 @default.
- W1956942179 cites W2010260089 @default.
- W1956942179 cites W2013427428 @default.
- W1956942179 cites W2016098462 @default.
- W1956942179 cites W2018637921 @default.
- W1956942179 cites W2022388005 @default.
- W1956942179 cites W2023271753 @default.
- W1956942179 cites W2025923613 @default.
- W1956942179 cites W2029088737 @default.
- W1956942179 cites W2034312345 @default.
- W1956942179 cites W2037433665 @default.
- W1956942179 cites W2038515816 @default.
- W1956942179 cites W2042990457 @default.
- W1956942179 cites W2047919899 @default.
- W1956942179 cites W2048845035 @default.
- W1956942179 cites W2063083444 @default.
- W1956942179 cites W2066132426 @default.
- W1956942179 cites W2070652699 @default.
- W1956942179 cites W2072266327 @default.
- W1956942179 cites W2072362976 @default.
- W1956942179 cites W2072745127 @default.
- W1956942179 cites W2076053237 @default.
- W1956942179 cites W2078388048 @default.
- W1956942179 cites W2078820708 @default.
- W1956942179 cites W2080749519 @default.
- W1956942179 cites W2086346447 @default.
- W1956942179 cites W2091529475 @default.
- W1956942179 cites W2142148187 @default.
- W1956942179 cites W2143981217 @default.
- W1956942179 cites W2260279736 @default.
- W1956942179 cites W2334040323 @default.
- W1956942179 cites W3083311034 @default.
- W1956942179 cites W4233674433 @default.
- W1956942179 cites W4236471684 @default.
- W1956942179 cites W4248821012 @default.
- W1956942179 doi "https://doi.org/10.1002/bbpc.199700001" @default.
- W1956942179 hasPublicationYear "1997" @default.
- W1956942179 type Work @default.
- W1956942179 sameAs 1956942179 @default.
- W1956942179 citedByCount "8" @default.
- W1956942179 countsByYear W19569421792020 @default.
- W1956942179 crossrefType "journal-article" @default.
- W1956942179 hasAuthorship W1956942179A5001016101 @default.
- W1956942179 hasAuthorship W1956942179A5001304596 @default.
- W1956942179 hasAuthorship W1956942179A5027004966 @default.
- W1956942179 hasAuthorship W1956942179A5049901030 @default.
- W1956942179 hasConcept C113196181 @default.
- W1956942179 hasConcept C121332964 @default.
- W1956942179 hasConcept C134121241 @default.
- W1956942179 hasConcept C135889238 @default.
- W1956942179 hasConcept C139066938 @default.
- W1956942179 hasConcept C147597530 @default.
- W1956942179 hasConcept C147789679 @default.
- W1956942179 hasConcept C148898269 @default.
- W1956942179 hasConcept C161790260 @default.
- W1956942179 hasConcept C178790620 @default.
- W1956942179 hasConcept C183971685 @default.
- W1956942179 hasConcept C185592680 @default.
- W1956942179 hasConcept C2781442258 @default.
- W1956942179 hasConcept C32891209 @default.
- W1956942179 hasConcept C32909587 @default.
- W1956942179 hasConcept C54582936 @default.
- W1956942179 hasConcept C62520636 @default.
- W1956942179 hasConcept C65024703 @default.
- W1956942179 hasConcept C75473681 @default.
- W1956942179 hasConcept C93391505 @default.
- W1956942179 hasConcept C97355855 @default.
- W1956942179 hasConceptScore W1956942179C113196181 @default.
- W1956942179 hasConceptScore W1956942179C121332964 @default.
- W1956942179 hasConceptScore W1956942179C134121241 @default.
- W1956942179 hasConceptScore W1956942179C135889238 @default.
- W1956942179 hasConceptScore W1956942179C139066938 @default.
- W1956942179 hasConceptScore W1956942179C147597530 @default.
- W1956942179 hasConceptScore W1956942179C147789679 @default.
- W1956942179 hasConceptScore W1956942179C148898269 @default.
- W1956942179 hasConceptScore W1956942179C161790260 @default.
- W1956942179 hasConceptScore W1956942179C178790620 @default.
- W1956942179 hasConceptScore W1956942179C183971685 @default.
- W1956942179 hasConceptScore W1956942179C185592680 @default.
- W1956942179 hasConceptScore W1956942179C2781442258 @default.