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• W1960052590 abstract "Abstract In the presence of activated MnO 2 , tert ‐butyl hydroperoxide (TBHP) in CH 2 Cl 2 is able to oxidize the allylic and benzylic methylene groups of different classes of compounds. I describe a one‐pot oxidation protocol based on two sequential steps. In the first step, carried out at low temperature, MnO 2 catalyses the oxidation of the methylene group. This is followed by a second step where reaction temperature is increased, allowing MnO 2 both to catalyse the decomposition of unreacted TBHP and to oxidize allylic alcohols that could possibly be formed. The proposed oxidation procedure is generally applicable, although its efficiency, regioselectivity, and chemoselectivity are strongly dependent on the structure of the substrate." @default.
• W1960052590 created "2016-06-24" @default.
• W1960052590 creator A5079657887 @default.
• W1960052590 date "2015-08-26" @default.
• W1960052590 modified "2023-10-10" @default.
• W1960052590 title "MnO₂/TBHP: A Versatile and User-­Friend­ly Combination of Reagents for the Oxidation of Allylic and Benzylic Methylene Functional Groups" @default.
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• W1960052590 doi "https://doi.org/10.1002/ejoc.201500829" @default.
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