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- W1960601715 abstract "The isomerization of the complex trans-meso-CH3Co(H2O)L2+ (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) to trans-primary, rac-CH3Co(H2O)L2+ has been investigated from pH range 7.11 to 8.09 in aqueous solution. The reaction rate law has been determined as: -d[meso-CH3Co(H2O)L2+]/dt = kOH [OH−][meso-CH3Co(H2O)L2+], where kOH = 600 ± 10 M−1s−1 at 25 °C and μ = 0.5 M. The activation parameters of the reaction were also studied with ΔH± = 19.1 ± 0.9 Kcal mol−1 and ΔS± = 18.0 ± 0.8 cal K−1mol−1. A mechanism that involves a secondary NH inversion is proposed." @default.
- W1960601715 created "2016-06-24" @default.
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- W1960601715 date "1998-12-01" @default.
- W1960601715 modified "2023-09-24" @default.
- W1960601715 title "Kinetics of the Base-Catalysed Isomerization of trans-meso-CH3Co(H2O)L2+(L = 5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)" @default.
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- W1960601715 doi "https://doi.org/10.1002/jccs.199800112" @default.
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