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- W196155248 abstract "The adsorption and dissociation of carbon monoxide on the (1120) face of a cobalt single crystal were studied in the range of temperatures from 300 to 470 K at pressures equal to or lower than 10−5 torr. Ultra violet photoelectron spectroscopy, Auger electron spectroscopy and thermal desorption spectroscopy were used to characterize the adsorbed species. The kinetics of the dissociation reaction were measured mainly on the basis of the variation of the work function. As found in a previous work on polycrystalline material, CO was found to dissociate to carbon and oxygen atoms. The activation energy for its dissociation was found to be 23±3 kcal/mole. The Co(1120) surface appears to be more reactive than other low index cobalt faces, but it is less reactive than the polycrystalline material. Our results confirm that the CO dissociation reaction is sensitive to the structure of the surface." @default.
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- W196155248 date "1989-01-01" @default.
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- W196155248 title "Adsorption and Dissociation of Carbon Monoxide on Co(1120)" @default.
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- W196155248 doi "https://doi.org/10.1016/s0167-2991(08)60669-2" @default.
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