Matches in SemOpenAlex for { <https://semopenalex.org/work/W1961641907> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W1961641907 abstract "μ-oxo-bis[tetrakis(t-butyl)phthalocyaninatoiron(III)] [130177-29-6] C96H96Fe2N16O (MW 1600.7) InChI = 1S/2C48H48N8.2Fe.O/c2*1-45(2,3)25-13-17-29-33(21-25)41-49-37(29)54-42-35-23-27(47(7,8)9)15-19-31(35)39(51-42)56-44-36-24-28(48(10,11)12)16-20-32(36)40(52-44)55-43-34-22-26(46(4,5)6)14-18-30(34)38(50-43)53-41;;;/h2*13-24H,1-12H3;;;/q2*-2;2*+2; InChIKey = NBXZGKWTAXJNKD-UHFFFAOYSA-N (catalyst for the oxidation of alcohols and aromatic hydrocarbons) Alternate Names: [(t-Bu4)PcFe]2O; μ-oxo-bis[tetra-tert-butylphthalocyaninatoiron(III)]; μ-oxo-bis[2,9,16,23-tetrakis(1,1-dimethylethyl)-29H,31H-phthalocyaninato(2−)-κN,29κN,30κN,31κN32]diiron; μ-oxo-bis[tetra-tert-butylphthalocyanineiron(III)]. Physical Data: Blue-green solid; mp >260 °C; δFe = 0.36, 0.23 mm s−1, ΔEQ = −0.44, +1.38 mm s−1, Rel. contribution = 15, 85% (measured in Mössbauer parameters); λabs (log ɛ) 290 (4.68), 360 (4.69), 598 (sh) (4.19), 686 (4.75) nm; gmin value = 2.007.1-3 Solubility: soluble in many nonpolar or weakly polar solvents.4 Preparative Method: condensation of (t-butyl)phthalonitrile and FeCl2 using DBU in n-pentanol afforded a blue-green μ-oxo dimer [(t-Bu4)PcFe]2O in 87% yield and characterized by Mössbauer spectroscopy.1 Also[(t-Bu4)PcFe]2O can be prepared via high-temperature coupling between 4-t-butyl phthalonitrile and FeSO4·H2O3 or iron(II) acetate.5" @default.
- W1961641907 created "2016-06-24" @default.
- W1961641907 creator A5016388549 @default.
- W1961641907 creator A5085307038 @default.
- W1961641907 creator A5091388322 @default.
- W1961641907 date "2013-09-16" @default.
- W1961641907 modified "2023-10-16" @default.
- W1961641907 title "μ-Oxo-bis[tetrakis(<i>t</i>-butyl)phthalocyaninatoiron(III)]" @default.
- W1961641907 cites W1970593129 @default.
- W1961641907 cites W2033488041 @default.
- W1961641907 cites W2052973214 @default.
- W1961641907 cites W2058562213 @default.
- W1961641907 cites W2062525072 @default.
- W1961641907 cites W2072004996 @default.
- W1961641907 cites W2074147214 @default.
- W1961641907 cites W2951152241 @default.
- W1961641907 cites W2951620998 @default.
- W1961641907 doi "https://doi.org/10.1002/047084289x.rn01595" @default.
- W1961641907 hasPublicationYear "2013" @default.
- W1961641907 type Work @default.
- W1961641907 sameAs 1961641907 @default.
- W1961641907 citedByCount "0" @default.
- W1961641907 crossrefType "reference-entry" @default.
- W1961641907 hasAuthorship W1961641907A5016388549 @default.
- W1961641907 hasAuthorship W1961641907A5085307038 @default.
- W1961641907 hasAuthorship W1961641907A5091388322 @default.
- W1961641907 hasConcept C134121241 @default.
- W1961641907 hasConcept C13965031 @default.
- W1961641907 hasConcept C155574463 @default.
- W1961641907 hasConcept C155647269 @default.
- W1961641907 hasConcept C161790260 @default.
- W1961641907 hasConcept C178790620 @default.
- W1961641907 hasConcept C185592680 @default.
- W1961641907 hasConcept C191897082 @default.
- W1961641907 hasConcept C192562407 @default.
- W1961641907 hasConcept C2778865537 @default.
- W1961641907 hasConcept C2779546866 @default.
- W1961641907 hasConcept C2780761128 @default.
- W1961641907 hasConcept C70854507 @default.
- W1961641907 hasConcept C8010536 @default.
- W1961641907 hasConceptScore W1961641907C134121241 @default.
- W1961641907 hasConceptScore W1961641907C13965031 @default.
- W1961641907 hasConceptScore W1961641907C155574463 @default.
- W1961641907 hasConceptScore W1961641907C155647269 @default.
- W1961641907 hasConceptScore W1961641907C161790260 @default.
- W1961641907 hasConceptScore W1961641907C178790620 @default.
- W1961641907 hasConceptScore W1961641907C185592680 @default.
- W1961641907 hasConceptScore W1961641907C191897082 @default.
- W1961641907 hasConceptScore W1961641907C192562407 @default.
- W1961641907 hasConceptScore W1961641907C2778865537 @default.
- W1961641907 hasConceptScore W1961641907C2779546866 @default.
- W1961641907 hasConceptScore W1961641907C2780761128 @default.
- W1961641907 hasConceptScore W1961641907C70854507 @default.
- W1961641907 hasConceptScore W1961641907C8010536 @default.
- W1961641907 hasLocation W19616419071 @default.
- W1961641907 hasOpenAccess W1961641907 @default.
- W1961641907 hasPrimaryLocation W19616419071 @default.
- W1961641907 hasRelatedWork W1983089792 @default.
- W1961641907 hasRelatedWork W2032876117 @default.
- W1961641907 hasRelatedWork W2097014657 @default.
- W1961641907 hasRelatedWork W2325193303 @default.
- W1961641907 hasRelatedWork W2356329570 @default.
- W1961641907 hasRelatedWork W2364482586 @default.
- W1961641907 hasRelatedWork W2365297458 @default.
- W1961641907 hasRelatedWork W2371080511 @default.
- W1961641907 hasRelatedWork W2383036295 @default.
- W1961641907 hasRelatedWork W4244266711 @default.
- W1961641907 isParatext "false" @default.
- W1961641907 isRetracted "false" @default.
- W1961641907 magId "1961641907" @default.
- W1961641907 workType "reference-entry" @default.