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• W1961859058 abstract "Non-heme iron(IV)-oxo species form iron(III) intermediates during hydrogen atom abstraction (HAA) from the C-H bond. While synthesizing a room temperature stable, electron rich, non-heme iron(IV)-oxo compound, we obtained iron(III)-hydroxide, iron(III)-alkoxide and hydroxylated-substrate-bound iron(II) as the detectable intermediates. The present study revealed that a radical rebound pathway was operative for benzylic C-H oxidation of ethylbenzene and cumene. A dissociative pathway for cyclohexane oxidation was established based on UV-vis and radical trap experiments. Interestingly, experimental evidence including O-18 labeling and mechanistic study suggested an electron transfer mechanism to be operative during C-H oxidation of alcohols (e.g. benzyl alcohol and cyclobutanol). The present report, therefore, unveils non-heme iron(IV)-oxo promoted substrate-dependent C-H oxidation pathways which are of synthetic as well as biological significance." @default.
• W1961859058 created "2016-06-24" @default.
• W1961859058 creator A5012345512 @default.
• W1961859058 creator A5051885484 @default.
• W1961859058 creator A5053069991 @default.
• W1961859058 date "2015-01-01" @default.
• W1961859058 modified "2023-09-24" @default.
• W1961859058 title "Mechanistic elucidation of C–H oxidation by electron rich non-heme iron(<scp>iv</scp>)–oxo at room temperature" @default.
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• W1961859058 doi "https://doi.org/10.1039/c5cc04803f" @default.
• W1961859058 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26277913" @default.
• W1961859058 hasPublicationYear "2015" @default.
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