Matches in SemOpenAlex for { <https://semopenalex.org/work/W1962199610> ?p ?o ?g. }
- W1962199610 abstract "[102691-36-1] C9H18ClN2OP (MW 236.68) InChI = 1S/C15H32N3OP/c1-12(2)17(13(3)4)20(19-11-9-10-16)18(14(5)6)15(7)8/h12-15H,9,11H2,1-8H3 InChIKey = RKVHNYJPIXOHRW-UHFFFAOYSA-N (reagent widely used for the phosphinylation of functional and reporter groups, ligands, and 3′-hydroxyls of modified and unmodified nucleosides for incorporation into oligonucleotides) Alternate Name: bis(N,N-diisopropylamino)-2-cyanoethoxyphosphine; (2-cyanoethoxy) bis(N,N-diisopropylamino)phosphine, 2-cyanoethyl N,N,N′,N′-tetraisopropylphosphordiamidite. Physical Data: bp 105–107 °C/0.4 mm Hg; d 1.04 g cm−3. Solubility: soluble in most organic solvents. Form Supplied in: colorless liquid. Analysis of Reagent Purity: 31P NMR; 1H NMR; elemental analysis. Preparative Methods: the reagent is prepared from the reaction of (2-cyanoethoxy)dichlorophosphine with N,N-diisopropylamine in anhydrous diethyl ether and isolated by vacuum distillation. Purification: can be purified by vacuum distillation. Handling, Storage, and Precautions: the reagent can be handled without decomposition under normal laboratory conditions and can be stored for months at −20 °C. Caution should be exercised when vacuum-distilling the reagent as it may explode if heated at a temperature (internal) exceeding 140 °C. Distillation should be carried out only if a vacuum of less than 0.5 mm Hg can be generated. Disposal: the reagent should first be carefully destroyed by slow addition to a stirred ethanolic solution of potassium hydroxide. The resulting solution can then be discarded in an appropriate chemical waste container." @default.
- W1962199610 created "2016-06-24" @default.
- W1962199610 creator A5022821865 @default.
- W1962199610 date "2003-10-15" @default.
- W1962199610 modified "2023-09-23" @default.
- W1962199610 title "2-Cyanoethyl Tetraisopropylphosphorodiamidite" @default.
- W1962199610 cites W1945712122 @default.
- W1962199610 cites W1963883610 @default.
- W1962199610 cites W1965454252 @default.
- W1962199610 cites W1965844530 @default.
- W1962199610 cites W1966419565 @default.
- W1962199610 cites W1967318475 @default.
- W1962199610 cites W1968344782 @default.
- W1962199610 cites W1969331072 @default.
- W1962199610 cites W1972015990 @default.
- W1962199610 cites W1974000484 @default.
- W1962199610 cites W1974635953 @default.
- W1962199610 cites W1980364293 @default.
- W1962199610 cites W1981120794 @default.
- W1962199610 cites W1981968225 @default.
- W1962199610 cites W1982010715 @default.
- W1962199610 cites W1983113264 @default.
- W1962199610 cites W1983870882 @default.
- W1962199610 cites W1986260159 @default.
- W1962199610 cites W1986666165 @default.
- W1962199610 cites W1986882083 @default.
- W1962199610 cites W1988728739 @default.
- W1962199610 cites W1988844434 @default.
- W1962199610 cites W1989330996 @default.
- W1962199610 cites W1989367342 @default.
- W1962199610 cites W1989701091 @default.
- W1962199610 cites W1990484859 @default.
- W1962199610 cites W1990979304 @default.
- W1962199610 cites W1991450104 @default.
- W1962199610 cites W1994539292 @default.
- W1962199610 cites W1996620320 @default.
- W1962199610 cites W1997100763 @default.
- W1962199610 cites W1997452120 @default.
- W1962199610 cites W2000744323 @default.
- W1962199610 cites W2001008114 @default.
- W1962199610 cites W2002220087 @default.
- W1962199610 cites W2006638735 @default.
- W1962199610 cites W2007689729 @default.
- W1962199610 cites W2008081852 @default.
- W1962199610 cites W2008819037 @default.
- W1962199610 cites W2008870170 @default.
- W1962199610 cites W2009296586 @default.
- W1962199610 cites W2013560552 @default.
- W1962199610 cites W2013851091 @default.
- W1962199610 cites W2015275505 @default.
- W1962199610 cites W2017451048 @default.
- W1962199610 cites W2023507019 @default.
- W1962199610 cites W2023771801 @default.
- W1962199610 cites W2024344426 @default.
- W1962199610 cites W2026710381 @default.
- W1962199610 cites W2028199339 @default.
- W1962199610 cites W2029416483 @default.
- W1962199610 cites W2029937993 @default.
- W1962199610 cites W2031493515 @default.
- W1962199610 cites W2032273236 @default.
- W1962199610 cites W2032782961 @default.
- W1962199610 cites W2036028450 @default.
- W1962199610 cites W2036133424 @default.
- W1962199610 cites W2036819090 @default.
- W1962199610 cites W2037705214 @default.
- W1962199610 cites W2040693229 @default.
- W1962199610 cites W2046771842 @default.
- W1962199610 cites W2048163675 @default.
- W1962199610 cites W2048733866 @default.
- W1962199610 cites W2049156424 @default.
- W1962199610 cites W2050738469 @default.
- W1962199610 cites W2051726230 @default.
- W1962199610 cites W2052371199 @default.
- W1962199610 cites W2054213866 @default.
- W1962199610 cites W2055112564 @default.
- W1962199610 cites W2058945255 @default.
- W1962199610 cites W2062322320 @default.
- W1962199610 cites W2064926019 @default.
- W1962199610 cites W2066516227 @default.
- W1962199610 cites W2067816361 @default.
- W1962199610 cites W2070440554 @default.
- W1962199610 cites W2071256242 @default.
- W1962199610 cites W2071349253 @default.
- W1962199610 cites W2071465854 @default.
- W1962199610 cites W2071671262 @default.
- W1962199610 cites W2074895162 @default.
- W1962199610 cites W2078671422 @default.
- W1962199610 cites W2079882285 @default.
- W1962199610 cites W2081228790 @default.
- W1962199610 cites W2082876841 @default.
- W1962199610 cites W2085730893 @default.
- W1962199610 cites W2088861350 @default.
- W1962199610 cites W2090513278 @default.
- W1962199610 cites W2091325898 @default.
- W1962199610 cites W2092555728 @default.
- W1962199610 cites W2093735774 @default.
- W1962199610 cites W2094285493 @default.
- W1962199610 cites W2094389832 @default.
- W1962199610 cites W2094938876 @default.
- W1962199610 cites W2095684647 @default.