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• W1962438323 abstract "Different boron weight percents on mixed-phase (anatase and rutile) TiO 2 nanoparticles were synthesized to investigate structure morphology, defect states, luminescence properties, and energy conversion. The measured results indicate that boron doping of TiO 2 both increases the crystallite size and rutile-phase percent in an anatase matrix. Decreasing the band gap by boron doping can extend the absorption to the visible region, while undoped TiO 2 exhibits high UV absorption. Oxygen vacancy defects generated by boron ions reduce Ti +4 and affect electron transport in dye-sensitized solar cells. Excess electrons originating from the oxygen vacancies of doped TiO 2 downward shift in the conduction band edge and prompt the transfer of photoelectrons from the conduction band of the rutile phase to the lower energy anatase trapping sites; they then separate charges to enhance the photocurrent and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:mrow><mml:msub><mml:mrow><mml:mi>J</mml:mi></mml:mrow><mml:mrow><mml:mtext>sc</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math>. Although the resistance of the electron recombination (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M2><mml:mrow><mml:msub><mml:mrow><mml:mi>R</mml:mi></mml:mrow><mml:mrow><mml:mi>k</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>) between doped TiO 2 photoanode and the electrolyte for the doped TiO 2 sample is lower, a longer electron lifetime (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M3><mml:mrow><mml:mi>τ</mml:mi></mml:mrow></mml:math>) of 19.7 ms with a higher electron density (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M4><mml:mrow><mml:msub><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mi>s</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>) of 2.1 × 10 18 cm −3 contributes to high solar conversion efficiency." @default.
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• W1962438323 date "2015-01-01" @default.
• W1962438323 modified "2023-10-15" @default.
• W1962438323 title "Characteristics of Boron Decorated TiO2Nanoparticles for Dye-Sensitized Solar Cell Photoanode" @default.
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• W1962438323 doi "https://doi.org/10.1155/2015/689702" @default.
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