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- W1963351170 abstract "(FeCl3) [7705-08-0] Cl3Fe (MW 162.20)InChI = 1S/3ClH.Fe/h3*1H;/q;;;+3/p-3InChIKey = RBTARNINKXHZNM-UHFFFAOYSA-K(Al2O3) [1344-28-1] Al2O3 (MW 101.96)InChI = 1S/2Al.3OInChIKey = TWNQGVIAIRXVLR-UHFFFAOYSA-N(proton scavenger; mild Lewis acid catalyst for ene reactions1, 2)Alternate Name: ferric chloride–alumina.Form Supplied in: the individual reagents are commercially available.Preparative Method: anhydrous Iron(III) Chloride (62 mmol) is added to anhydrous CH2Cl2 (160 mL) under argon. The mixture is stirred vigorously while 50 g chromatography grade basic Alumina is added in small portions under argon. Stirring is continued for 1 h to obtain homogeneous adsorbtion and the solvent is then removed under reduced pressure. The basic alumina supported FeCl3 obtained can be stored under argon for several months without loss of catalytic activity.Handling, Storage, and Precautions: should be stored and manipulated in an inert, dry atmosphere; FeCl3 is hygroscopic and corrosive, inhalation or ingestion may be fatal; basic alumina is an irritant. Use in a fume hood." @default.
- W1963351170 created "2016-06-24" @default.
- W1963351170 creator A5016077667 @default.
- W1963351170 date "2001-04-15" @default.
- W1963351170 modified "2023-09-26" @default.
- W1963351170 title "Iron(III) Chloride-Alumina" @default.
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- W1963351170 doi "https://doi.org/10.1002/047084289x.ri057" @default.
- W1963351170 hasPublicationYear "2001" @default.
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