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- W1963485402 abstract "Stereospecific total synthesis of chromomoric acid C-I and C-II methyl esters and delicate elucidation of their structures have been reported. A stereospecific five-step synthesis, starting from enone 5, with one-pot three-component coupling and retro Diels-Alder reaction as the key reactions provided a target molecule which was proved to be chromomoric acid C-I methyl ester (1), but its physical data were identical with that of the natural product originally assigned to be chromomoric acid C-IV methyl ester (4). Structural elucidation with a lanthanide shift reagent showed the original assignment should be revised to 1. Total synthesis and structural confirmation of chromomoric acid C-II methyl ester (2) was thereafter fulfilled." @default.
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- W1963485402 date "1994-01-01" @default.
- W1963485402 modified "2023-10-10" @default.
- W1963485402 title "Total synthesis and structural revision of chromomoric acid C-I and C-II methyl esters" @default.
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- W1963485402 doi "https://doi.org/10.1016/s0040-4020(01)89543-0" @default.
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