Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963486098> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W1963486098 endingPage "874" @default.
- W1963486098 startingPage "864" @default.
- W1963486098 abstract "Kraitchman has shown that a single isotopic substitution on an atom is sufficient to determine directly the coordinates of that atom with respect to the principal axes of the original molecule. Kraitchman's formulas represent exact solutions of the equations for the equilibrium moments of inertia. However, the effects of the zero‐point vibrations are such that the coordinates obtained by substitution from the ground state moments of inertia I0 are systematically less than r0. These coordinates have here been called r (substitution) or rs, and it is found that rs≃(r0+re)/2, and Is= ∑ imirsi2≃(I0+Ie)/2.In the usual method of solution, the coordinate of one atom is determined from the equation for I0, and therefore the difference I0—Is must be made up by this one coordinate. This introduces a large error in the structures normally determined from ground state constants, and results in variations of 0.01 A in structures determined from different sets of isotopic species. If instead, we obtain the structure on..." @default.
- W1963486098 created "2016-06-24" @default.
- W1963486098 creator A5026624374 @default.
- W1963486098 date "1958-10-01" @default.
- W1963486098 modified "2023-10-17" @default.
- W1963486098 title "Determination of Molecular Structures from Ground State Rotational Constants" @default.
- W1963486098 cites W1497143467 @default.
- W1963486098 cites W1511246523 @default.
- W1963486098 cites W1972492797 @default.
- W1963486098 cites W1974882720 @default.
- W1963486098 cites W1994618748 @default.
- W1963486098 cites W1998104057 @default.
- W1963486098 cites W2006190880 @default.
- W1963486098 cites W2024331545 @default.
- W1963486098 cites W2032756143 @default.
- W1963486098 cites W2037778122 @default.
- W1963486098 cites W2042415079 @default.
- W1963486098 cites W2042772188 @default.
- W1963486098 cites W2043068645 @default.
- W1963486098 cites W2069760857 @default.
- W1963486098 cites W2089773530 @default.
- W1963486098 cites W4240378667 @default.
- W1963486098 doi "https://doi.org/10.1063/1.1744602" @default.
- W1963486098 hasPublicationYear "1958" @default.
- W1963486098 type Work @default.
- W1963486098 sameAs 1963486098 @default.
- W1963486098 citedByCount "937" @default.
- W1963486098 countsByYear W19634860982012 @default.
- W1963486098 countsByYear W19634860982013 @default.
- W1963486098 countsByYear W19634860982014 @default.
- W1963486098 countsByYear W19634860982015 @default.
- W1963486098 countsByYear W19634860982016 @default.
- W1963486098 countsByYear W19634860982017 @default.
- W1963486098 countsByYear W19634860982018 @default.
- W1963486098 countsByYear W19634860982019 @default.
- W1963486098 countsByYear W19634860982020 @default.
- W1963486098 countsByYear W19634860982021 @default.
- W1963486098 countsByYear W19634860982022 @default.
- W1963486098 countsByYear W19634860982023 @default.
- W1963486098 crossrefType "journal-article" @default.
- W1963486098 hasAuthorship W1963486098A5026624374 @default.
- W1963486098 hasConcept C121332964 @default.
- W1963486098 hasConcept C147597530 @default.
- W1963486098 hasConcept C184779094 @default.
- W1963486098 hasConcept C185592680 @default.
- W1963486098 hasConcept C69523127 @default.
- W1963486098 hasConceptScore W1963486098C121332964 @default.
- W1963486098 hasConceptScore W1963486098C147597530 @default.
- W1963486098 hasConceptScore W1963486098C184779094 @default.
- W1963486098 hasConceptScore W1963486098C185592680 @default.
- W1963486098 hasConceptScore W1963486098C69523127 @default.
- W1963486098 hasIssue "4" @default.
- W1963486098 hasLocation W19634860981 @default.
- W1963486098 hasOpenAccess W1963486098 @default.
- W1963486098 hasPrimaryLocation W19634860981 @default.
- W1963486098 hasRelatedWork W1966972082 @default.
- W1963486098 hasRelatedWork W1980229862 @default.
- W1963486098 hasRelatedWork W1999339278 @default.
- W1963486098 hasRelatedWork W2003166081 @default.
- W1963486098 hasRelatedWork W2022969243 @default.
- W1963486098 hasRelatedWork W2080777994 @default.
- W1963486098 hasRelatedWork W2083633935 @default.
- W1963486098 hasRelatedWork W2296353051 @default.
- W1963486098 hasRelatedWork W2327447609 @default.
- W1963486098 hasRelatedWork W2519656836 @default.
- W1963486098 hasVolume "29" @default.
- W1963486098 isParatext "false" @default.
- W1963486098 isRetracted "false" @default.
- W1963486098 magId "1963486098" @default.
- W1963486098 workType "article" @default.