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- W1963486191 abstract "Arylsilanes are useful intermediates in organic synthesis, which might be used, for instance, as nucleophiles in aryl-aryl cross-coupling as well as in a number of other transition-metal-catalyzed coupling reactions. The search for a direct route toward these compounds from aryl halides, avoiding too reactive aryllithium or -magnesium intermediates attracts recently significant attention. So far, such a transformation has been successfully performed only on electron-rich aryl iodides, using Pd as catalyst. This method is complementary with the previously described protocols, and covers a larger scope of the substrates, including those bearing highly susceptible functional groups like nitro or aldehyde." @default.
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- W1963486191 date "2006-05-01" @default.
- W1963486191 modified "2023-10-18" @default.
- W1963486191 title "Platinum Oxide Catalyzed Silylation of Aryl Halides with Triethylsilane" @default.
- W1963486191 doi "https://doi.org/10.1055/s-2006-934419" @default.
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