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- W1963506539 abstract "Abstract Vinyl polymer/polyurethane hybrid latex particles with various compositions were successfully prepared via emulsion polymerization of vinyl monomer in the presence of self-emulsified polyurethane dispersion without using any surfactant. Studies were carried out on polymerization kinetics, characterization of the hybrid particles and the physical properties of nano-sized vinyl polymer particle/thermoplastic polyurethane blends. It was found that the maximum content of vinyl polymer in polyurethane hybrid particles was up to 80 percent and all of the vinyl polymer/polyurethane hybrid particles were less than 120 nm. Infrared spectroscopy, thermal gravimetric analysis and differential scanning calorimetry analysis indicated the influence of vinyl polymer on the polyurethane hybrid particles. With the polyurethane shells outside and, therefore, good compatibility with polyurethane matrix, the hybrid particles can be easily blended into polyurethane matrix. Some unusual changes of dynamic mechanical properties in the low temperature region were found in the blends of hybrid particles and thermoplastic polyurethane. With the addition of only 3%, the mechanical properties of these blends did not show a significant change. This study provided a new method to prepare hybrid particles in the absence of surfactant and made an attempt on application of vinyl polymer/polyurethane hybrid particles in the blending modification" @default.
- W1963506539 created "2016-06-24" @default.
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- W1963506539 date "2010-12-01" @default.
- W1963506539 modified "2023-09-24" @default.
- W1963506539 title "Preparation of vinyl polymer/polyurethane hybrid latex particles and their application in nano-sized vinyl polymer particle/thermoplastic polyurethane blends" @default.
- W1963506539 doi "https://doi.org/10.1515/epoly.2010.10.1.1110" @default.
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