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• W1963513135 abstract "Abstract Europium-doped borosilicate glasses were prepared by melt-quenching procedure in the air. The mixed valence of Eu 2+ and Eu 3+ was identified by photo luminescence spectrum and electron paramagnetic resonance (EPR). The existence of mixed valence was observed owing to the unequivalent substitution and de-polymerization network of the as-prepared borosilicate glasses. The variation of the glass composition in B 2 O 3 /BaO ratios changed the stability of the Eu 3+ ions distinctly. In particular, as-prepared borosilicate glasses exhibited a tri-wavelength light excitable spectra centered at 397, 466 and 534 nm to give the broadened orange-red emission at around 592 and 617 nm, due to supersensitive transitions of Eu 3+ ions. This simultaneous tri-wavelength excitation happened to correspond with the emitting wavelength from near ultraviolet, blue AlInGaN chips and that from YAG:Ce 3+ . The total quantum yield (QY) of the Eu-doped glasses under 466 nm excitation was evaluated to be 10%, potentially providing a versatile combination with the europium-doped borosilicate glasses for red component addition to improve the quality of white light." @default.
• W1963513135 created "2016-06-24" @default.
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• W1963513135 date "2012-05-01" @default.
• W1963513135 modified "2023-09-23" @default.
• W1963513135 title "Multi-wavelength excitable europium-doped borosilicate glasses for orange-red emission: composition-induced structure and valence variation" @default.
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• W1963513135 doi "https://doi.org/10.1016/s1002-0721(12)60062-3" @default.
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