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- W1963516174 abstract "The mesophasic behaviour of the following compounds has been investigated by DSC, X-ray diffraction and optical microscopy methods: CH3(CH2)4-CO-R-A n -R-CO-(CH2)4-CH3,n=9→ 14, 16 CH3(CH2)4-CO-R-B n -R-CO-(CH2)4-CH3,n=2, 3A n=-CO-O-(CH2)n−4-O-CO-,B n =-CO-(OCH2CH2) n -O-CO-,R=-O-Ø-C(CH3)=N-N=(CH3)C-Ø-O-,Ø=-C6H4 They have been assumed to be low molecular weight models of homologous nematogenic polymers. All the examined compounds exhibit nematic mesomorphism. On complete analogy with the corresponding polymers, the thermodynamic data relative to the nematic-isotropic phase transition show a very reduced, if any, odd-even fluctuation. These data are compared with those obtained for very similar compounds, both polymeric and non-polymeric, containing ester linkages between the rigid and flexible groups, to provide evidence of the reliability of the dimeric compounds as models of the polymeric homologues." @default.
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- W1963516174 date "1985-11-01" @default.
- W1963516174 modified "2023-10-01" @default.
- W1963516174 title "Mesophasic properties of low molecular weight analogues of nematogenic polycarbonates" @default.
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- W1963516174 doi "https://doi.org/10.1007/bf01914301" @default.
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