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- W1963519145 abstract "The effect exercised by substituents on the velocity of electrophilic and nucleophilic substitution reactions of benzene derivatives is discussed in the light of a theoretical treatment of the inductive effect2). The theory is checked against the bromination of substituted phenols and the reaction velocity of piperidine with 2-nitrobromobenzenes substituted in the 4-position. A linear relationship exists between the logarithm of the reaction velocity and the effect of the substituent on the activation energy of the reaction (as calculated from the theory)." @default.
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- W1963519145 date "2010-09-02" @default.
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- W1963519145 title "On the theory of aromatic substitution: III. Reactivity in electrophilic and nucleophilic substitution reactions" @default.
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- W1963519145 doi "https://doi.org/10.1002/recl.19530720616" @default.
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