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- W1963527816 abstract "Using potential energy surface information from BAC-MP4 calculations and statistical-dynamical methods, we have calculated the branching fraction for the NH+NO reaction, NH+NO→N2+OH (1) →N2O+H. (2) We find that reaction (2) dominates over the entire temperature range considered, 300 K<T<3500 K, with f=k1/(k1+k2) varying from about 0.19 at room temperature to about 0.30 at 3500 K. In addition, we have calculated rate coefficients for the two-channel process, NH+O2→HNO+O (3) →NO+OH. (4) In this case we find that reaction (4) dominates at low temperature, reaction (3) at high temperature. Between 300 K and 3300 K these rate coefficients can be expressed as (cm3/mole-sec) k3=4.61×105 T2.0 exp (−6500/RT) and k4=1.28×106 T1.5 exp (−100/RT). All these results are in good agreement with available experimental data." @default.
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- W1963527816 date "1992-01-01" @default.
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- W1963527816 title "The reactions of imidogen with nitric oxide and molecular oxygen" @default.
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- W1963527816 doi "https://doi.org/10.1016/s0082-0784(06)80088-3" @default.
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