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- W1963530089 abstract "The radiolysis of N 2 O saturated-aqueous solutions of benzene- 14 C has been examined using radio-liquid chromatographic methods to follow the quantitative aspects of the reactions of hydroxycyclohexadienyl radicals. In the absence of a radical oxidant, at least five important products are produced. The total yield of 5.8 observed for the incorporation of benzene into products accounts for essentially all of the radicals initially produced from the water. Dimeric products predominate with a total yield of 4.1. Phenol is produced with a yield of only 0.8 indicating a disproportionation/combination ratio for hydroxycyclohexadienyl radicals of ⪕0.4. In the presence of 2 m m ferricyanide the hydroxycyclohexadienyl radicals are quantitatively oxidized to phenol with no trace (<1%) remaining of dimeric or other high molecular weight products. The initial yield for phenol formation (6.0 molecules/100 eV) provides a measure for OH production in N 2 O saturated aqueous solutions." @default.
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- W1963530089 date "1978-01-01" @default.
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- W1963530089 title "Oxidation of benzene by radiolytically produced OH radicals" @default.
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- W1963530089 doi "https://doi.org/10.1016/0146-5724(78)90078-x" @default.
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