FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963535364> ?p ?o ?g. }

• W1963535364 endingPage "169" @default.
• W1963535364 startingPage "163" @default.
• W1963535364 abstract "Abstract The syntheses and single-crystal X-ray structures of several well-defined hexaphenyltrisiloxanediolates of sodium, titanium, and iron are reported. All these compounds contain eight-membered MSi 3 O 4 rings (M = Na, Ti, Fe). Treatment of 1,1,3,3-tetraphenyldisiloxane-1,3-diol, (HO)SiPh 2 OSiPh 2 (OH) ( 1 ), with excess metallic Na in THF afforded the sodium-hexaphenyltrisiloxandiolate reagent [Ph 2 Si(OSiPh 2 O) 2 ] 2 Na 4 (THF) 4 ( 3a ) in 68% yield. Single crystals suitable for X-ray diffraction were obtained for the diglyme solvate [Ph 2 Si(OSiPh 2 O) 2 ] 2 Na 4 (diglyme) 2 ( 3b ) which was prepared in 76% yield by recrystallization of 3a from diglyme (=ethylene-bis(2-methoxyethyl)ether). Readily accessible 3a has been demonstrated to be a highly useful precursor for new transition metal hexaphenyltrisiloxanediolates (=metallacyclotetrasiloxanes). Reaction of 3a with an excess of TiCl 4 in THF provided the titanacyclotetrasiloxane derivative [Ph 2 Si(OSiPh 2 O) 2 ]TiCl 2 (THF) 2 ( 4 ) with octahedral coordination around titanium. Similar reaction of 3a with FeCl 3 in THF afforded the anionic spirocyclic iron(III) complex [Na(DME) 3 ][{Ph 2 Si(OSiPh 2 O) 2 } 2 Fe] ( 5 ) as yellow-brown crystals in 71% yield. An iron(III) analog of 4 , the anionic ferracyclotetrasiloxane complex [Li(DME) 3 ][Ph 2 Si(OSiPh 2 O) 2 FeCl 2 ] ( 6 ) was prepared in moderate yield (53%) by deprotonation of 1,1,3,3,5,5-hexaphenyl-1,3,5-trisiloxanediol, Ph 2 Si(OSiPh 2 OH) 2 ( 2 ), with n -butyllithium followed by reaction with FeCl 3 in DME. The molecular and crystal structures of 3b , 4 , 5 , and 6 have been determined by X-ray diffraction." @default.
• W1963535364 created "2016-06-24" @default.
• W1963535364 creator A5005752122 @default.
• W1963535364 creator A5019140353 @default.
• W1963535364 creator A5037534218 @default.
• W1963535364 creator A5047069323 @default.
• W1963535364 creator A5069558116 @default.
• W1963535364 creator A5082029428 @default.
• W1963535364 date "2015-01-01" @default.
• W1963535364 modified "2023-09-25" @default.
• W1963535364 title "Synthesis and structure of hexaphenyltrisiloxanediolates of sodium, titanium, and iron" @default.
• W1963535364 cites W1497203977 @default.
• W1963535364 cites W1498116839 @default.
• W1963535364 cites W1587703714 @default.
• W1963535364 cites W18411142 @default.
• W1963535364 cites W1963572919 @default.
• W1963535364 cites W1966148146 @default.
• W1963535364 cites W1967799039 @default.
• W1963535364 cites W1968507936 @default.
• W1963535364 cites W1970343163 @default.
• W1963535364 cites W1970548665 @default.
• W1963535364 cites W1970784732 @default.
• W1963535364 cites W1979263948 @default.
• W1963535364 cites W1984145070 @default.
• W1963535364 cites W1984726784 @default.
• W1963535364 cites W1985393499 @default.
• W1963535364 cites W1986525697 @default.
• W1963535364 cites W1988921999 @default.
• W1963535364 cites W1991333855 @default.
• W1963535364 cites W1991475924 @default.
• W1963535364 cites W1995606776 @default.
• W1963535364 cites W1996106553 @default.
• W1963535364 cites W1997594281 @default.
• W1963535364 cites W1998987092 @default.
• W1963535364 cites W1999992121 @default.
• W1963535364 cites W2001765196 @default.
• W1963535364 cites W2003066172 @default.
• W1963535364 cites W2006116857 @default.
• W1963535364 cites W2006600679 @default.
• W1963535364 cites W2007087115 @default.
• W1963535364 cites W2008106235 @default.
• W1963535364 cites W2009379989 @default.
• W1963535364 cites W2012289582 @default.
• W1963535364 cites W2013299343 @default.
• W1963535364 cites W2013501137 @default.
• W1963535364 cites W2013768143 @default.
• W1963535364 cites W2014327298 @default.
• W1963535364 cites W2015235674 @default.
• W1963535364 cites W2016436640 @default.
• W1963535364 cites W2017177787 @default.
• W1963535364 cites W2019262592 @default.
• W1963535364 cites W2019263572 @default.
• W1963535364 cites W2021411333 @default.
• W1963535364 cites W2021628565 @default.
• W1963535364 cites W2022776492 @default.
• W1963535364 cites W2031026779 @default.
• W1963535364 cites W2034355791 @default.
• W1963535364 cites W2036427380 @default.
• W1963535364 cites W2045501108 @default.
• W1963535364 cites W2045775441 @default.
• W1963535364 cites W2046371922 @default.
• W1963535364 cites W2051573892 @default.
• W1963535364 cites W2051909060 @default.
• W1963535364 cites W2052727444 @default.
• W1963535364 cites W2054338158 @default.
• W1963535364 cites W2059199735 @default.
• W1963535364 cites W2061232937 @default.
• W1963535364 cites W2064383929 @default.
• W1963535364 cites W2069908440 @default.
• W1963535364 cites W2080908761 @default.
• W1963535364 cites W2081342257 @default.
• W1963535364 cites W2081772674 @default.
• W1963535364 cites W2082202562 @default.
• W1963535364 cites W2084144037 @default.
• W1963535364 cites W2087572285 @default.
• W1963535364 cites W2088739700 @default.
• W1963535364 cites W2088886367 @default.
• W1963535364 cites W2090688328 @default.
• W1963535364 cites W2094212542 @default.
• W1963535364 cites W2094511655 @default.
• W1963535364 cites W2105737662 @default.
• W1963535364 cites W2107185106 @default.
• W1963535364 cites W2115449850 @default.
• W1963535364 cites W2116541043 @default.
• W1963535364 cites W2117975016 @default.
• W1963535364 cites W2132834537 @default.
• W1963535364 cites W2138626427 @default.
• W1963535364 cites W2143945175 @default.
• W1963535364 cites W2146497364 @default.
• W1963535364 cites W2152471584 @default.
• W1963535364 cites W2159477700 @default.
• W1963535364 cites W2170903119 @default.
• W1963535364 cites W2317319005 @default.
• W1963535364 cites W2320780710 @default.
• W1963535364 cites W2322550264 @default.
• W1963535364 cites W2327275956 @default.
• W1963535364 cites W2521702899 @default.
• W1963535364 cites W2951044804 @default.

• next