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• W1963535765 abstract "Three functionalized ionic liquids (ILs), tetrabutylammonium di(2-ethylhexyl)phosphate ([TBA][DEHP]), trioctylmethylammonium di(2-ethylhexyl)phosphate ([TOMA][DEHP]), and trihexyl(tetradecyl)phosphonium di(2-ethylhexyl)phosphate ([THTP][DEHP]), are synthesized and characterized. These ILs are used as DEHP-based ionic extractants and are investigated for rare earth elements (REEs) separation in 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C6mim][NTf2]) and diisopropylbenzene (DIPB) along with di(2-ethylhexyl)phosphoric acid (HDEHP). Solubilities of the DEHP-based ionic extractants in [C6mim][NTf2] are much better than that of HDEHP in [C6mim][NTf2]. We herein report the achievement of enhanced extractabilities and selectivities for separation of REEs using DEHP-based ionic extractants in [C6mim][NTf2]. This work highlights the potential of developing a comprehensive ionic liquid-based extraction strategy for REEs using ionic liquids as both extractant and diluent." @default.
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• W1963535765 date "2012-02-01" @default.
• W1963535765 modified "2023-10-16" @default.
• W1963535765 title "Solvent extraction of rare-earth ions based on functionalized ionic liquids" @default.
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• W1963535765 doi "https://doi.org/10.1016/j.talanta.2011.12.069" @default.
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