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- W1963535933 abstract "The reaction of CrCl3 with 3 equiv of the cycloheptadienyl anion leads to Cr(η7-C7H7)(η4-C7H10) (C7H10 = cycloheptadiene), through a process in which one ligand loses two hydrogen atoms while the other ligand gains one. The same complex had been reported from an entirely different route, involving the reaction of chromium(III) salts with Grignard reagents in the presence of cycloheptadiene and cycloheptatriene. The formulation of the complex has been confirmed by a low-temperature X-ray diffraction study. Related reactions have been found to lead to M(η7-C7H7)(η5-C7H9) (M = Ti, V; C7H9 = cycloheptadienyl) complexes. The preferential formation of one aromatic ηn-CnHn ligand seems to provide the driving force favoring the isolated products and related species having other values of n." @default.
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- W1963535933 date "2003-01-18" @default.
- W1963535933 modified "2023-10-04" @default.
- W1963535933 title "Reaction of Chromium(III) Chloride with the Cycloheptadienyl Anion: Susceptibility of Edge Bridges To C−H Activation Reactions" @default.
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- W1963535933 doi "https://doi.org/10.1021/om020991k" @default.
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