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- W1963536769 abstract "The crystal structure of 2,2′-bipyridinium tetrabromocobaltate(II) has been established by successive Fourier analyses. The atomic parameters were refined by least-squares techniques, using the three-dimensional X-ray data, to an R factor of 0.127 for 1461 non-zero reflections. The complex crystallizes in the space group P21/c with four formula units in the unit cell with dimensions of a=8.42, b=14.00, c=12.88 Å, and β=98.7°. The crystal consists of slightly distorted tetrahedral [CoBr4]2− anions and 2,2′-bipyridinium cations, in which two pyridinium ring planes are inclined toward one another at an angle of 39°. The two N+–H groups in the cation participate in N+–H···Br− type hydrogen bonds (N···Br=3.23 Å and 3.31 Å). The mean value of the four Co–Br bond lengths is 2.42 Å." @default.
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- W1963536769 date "1971-06-01" @default.
- W1963536769 modified "2023-09-25" @default.
- W1963536769 title "The Crystal Structure of 2,2′-Bipyridinium Tetrabromocobaltate(II)" @default.
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- W1963536769 doi "https://doi.org/10.1246/bcsj.44.1597" @default.
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