FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963550232> ?p ?o ?g. }

• W1963550232 endingPage "2698" @default.
• W1963550232 startingPage "2694" @default.
• W1963550232 abstract "1H NMR saturation transfer and T1 experiments were used to monitor the amide hydrogen exchange rates of 2,5-piperazinedione (diketopiperazine, DKP) and 2-piperidone (δ-valerolactam) in water. Specific acid-catalyzed exchange rate constants (kH) for δ-valerolactam and DKP are quite similar, but DKP exhibits an approximately 740-fold larger specific base-catalyzed rate constant (kOH) at 25 °C, which approaches the diffusion limit. The rate constants for DKP are larger than expected from simple inductive effects. The enhanced rate constants for DKP are attributed to electrostatic interactions involving the second peptide group. In general, the exchange data and inspection of protein structures suggest that such electrostatic interactions may have significant effects on hydrogen exchange in proteins." @default.
• W1963550232 created "2016-06-24" @default.
• W1963550232 creator A5021937139 @default.
• W1963550232 creator A5058479824 @default.
• W1963550232 date "1996-01-01" @default.
• W1963550232 modified "2023-09-25" @default.
• W1963550232 title "Intramolecular Electrostatic Interactions Accelerate Hydrogen Exchange in Diketopiperazine Relative to 2-Piperidone" @default.
• W1963550232 cites W1037891263 @default.
• W1963550232 cites W1495408300 @default.
• W1963550232 cites W1963736337 @default.
• W1963550232 cites W1968360065 @default.
• W1963550232 cites W1971251199 @default.
• W1963550232 cites W1974485738 @default.
• W1963550232 cites W1975160123 @default.
• W1963550232 cites W1976581217 @default.
• W1963550232 cites W1980952413 @default.
• W1963550232 cites W1981134448 @default.
• W1963550232 cites W1985681568 @default.
• W1963550232 cites W1993085810 @default.
• W1963550232 cites W2007415752 @default.
• W1963550232 cites W2008708467 @default.
• W1963550232 cites W2012451447 @default.
• W1963550232 cites W2020716464 @default.
• W1963550232 cites W2024706925 @default.
• W1963550232 cites W2030841140 @default.
• W1963550232 cites W2032737277 @default.
• W1963550232 cites W2040612759 @default.
• W1963550232 cites W2043120885 @default.
• W1963550232 cites W2049613956 @default.
• W1963550232 cites W2051318068 @default.
• W1963550232 cites W2052776513 @default.
• W1963550232 cites W2055320632 @default.
• W1963550232 cites W2056230979 @default.
• W1963550232 cites W2062834515 @default.
• W1963550232 cites W2067815064 @default.
• W1963550232 cites W2075077136 @default.
• W1963550232 cites W2076063335 @default.
• W1963550232 cites W2078392132 @default.
• W1963550232 cites W2091097441 @default.
• W1963550232 cites W2091114929 @default.
• W1963550232 cites W2109703770 @default.
• W1963550232 cites W2127400370 @default.
• W1963550232 cites W2177431260 @default.
• W1963550232 cites W251070167 @default.
• W1963550232 cites W2952842382 @default.
• W1963550232 cites W33171901 @default.
• W1963550232 cites W995681685 @default.
• W1963550232 doi "https://doi.org/10.1021/ja952892m" @default.
• W1963550232 hasPublicationYear "1996" @default.
• W1963550232 type Work @default.
• W1963550232 sameAs 1963550232 @default.
• W1963550232 citedByCount "10" @default.
• W1963550232 countsByYear W19635502322020 @default.
• W1963550232 countsByYear W19635502322022 @default.
• W1963550232 crossrefType "journal-article" @default.
• W1963550232 hasAuthorship W1963550232A5021937139 @default.
• W1963550232 hasAuthorship W1963550232A5058479824 @default.
• W1963550232 hasConcept C112887158 @default.
• W1963550232 hasConcept C121332964 @default.
• W1963550232 hasConcept C147597530 @default.
• W1963550232 hasConcept C147789679 @default.
• W1963550232 hasConcept C148898269 @default.
• W1963550232 hasConcept C178790620 @default.
• W1963550232 hasConcept C185592680 @default.
• W1963550232 hasConcept C2778439535 @default.
• W1963550232 hasConcept C32909587 @default.
• W1963550232 hasConcept C512968161 @default.
• W1963550232 hasConcept C62520636 @default.
• W1963550232 hasConcept C69357855 @default.
• W1963550232 hasConcept C71240020 @default.
• W1963550232 hasConcept C75079739 @default.
• W1963550232 hasConcept C93391505 @default.
• W1963550232 hasConcept C97355855 @default.
• W1963550232 hasConceptScore W1963550232C112887158 @default.
• W1963550232 hasConceptScore W1963550232C121332964 @default.
• W1963550232 hasConceptScore W1963550232C147597530 @default.
• W1963550232 hasConceptScore W1963550232C147789679 @default.
• W1963550232 hasConceptScore W1963550232C148898269 @default.
• W1963550232 hasConceptScore W1963550232C178790620 @default.
• W1963550232 hasConceptScore W1963550232C185592680 @default.
• W1963550232 hasConceptScore W1963550232C2778439535 @default.
• W1963550232 hasConceptScore W1963550232C32909587 @default.
• W1963550232 hasConceptScore W1963550232C512968161 @default.
• W1963550232 hasConceptScore W1963550232C62520636 @default.
• W1963550232 hasConceptScore W1963550232C69357855 @default.
• W1963550232 hasConceptScore W1963550232C71240020 @default.
• W1963550232 hasConceptScore W1963550232C75079739 @default.
• W1963550232 hasConceptScore W1963550232C93391505 @default.
• W1963550232 hasConceptScore W1963550232C97355855 @default.
• W1963550232 hasIssue "11" @default.
• W1963550232 hasLocation W19635502321 @default.
• W1963550232 hasOpenAccess W1963550232 @default.
• W1963550232 hasPrimaryLocation W19635502321 @default.
• W1963550232 hasRelatedWork W1969908309 @default.
• W1963550232 hasRelatedWork W1979353479 @default.
• W1963550232 hasRelatedWork W1999197776 @default.
• W1963550232 hasRelatedWork W2003290000 @default.
• W1963550232 hasRelatedWork W2030749276 @default.

• next