Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963555901> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W1963555901 endingPage "11265" @default.
- W1963555901 startingPage "11264" @default.
- W1963555901 abstract "Magnesocene adducts of alkylamines were prepared and characterized. Treatment of 3-amino-2,4-dimethylpentane, isopropylamine, tert-butylamine, benzylamine, or N-isopropylbenzylamine with magnesocene at ambient temperature in toluene afforded the amine adducts Cp2Mg(NH2CH(CH(CH3)2)2) (91%), Cp2Mg(NH2iPr) (80%), Cp2Mg(NH2tBu) (67%), Cp2Mg(NH2CH2Ph) (80%), and Cp2Mg(NH(CH(CH3)2)(CH2C6H5)) (91%). These adducts are stable at ambient temperature, and Cp2Mg(NH2CH(CH(CH3)2)2) can be sublimed at 60 degrees C/0.05 Torr without any evidence for reversion to magnesocene. The solid-state structure of Cp2Mg(NH2CH(CH(CH3)2)2) contains eta5- and eta2-cyclopentadienyl ligands, and the hydrogen atoms on the coordinated amine nitrogen atom participate in intramolecular and intermolecular hydrogen bonding to the eta2-cyclopentadienyl ligand. The observed hydrogen bonding is relevant to the path by which cyclopentadiene is eliminated from metal cyclopentadienyl CVD source compounds during film growth employing acidic element hydrides as co-reactants." @default.
- W1963555901 created "2016-06-24" @default.
- W1963555901 creator A5013652065 @default.
- W1963555901 creator A5042708314 @default.
- W1963555901 creator A5071729996 @default.
- W1963555901 date "2002-08-29" @default.
- W1963555901 modified "2023-09-27" @default.
- W1963555901 title "Intramolecular and Intermolecular N−H···C<sub>5</sub>H<sub>5</sub><sup>-</sup> Hydrogen Bonding in Magnesocene Adducts of Alkylamines. Implications for Chemical Vapor Deposition Using Cyclopentadienyl Source Compounds" @default.
- W1963555901 cites W1978235347 @default.
- W1963555901 cites W2004681142 @default.
- W1963555901 cites W2013741265 @default.
- W1963555901 cites W2015906461 @default.
- W1963555901 cites W2022994634 @default.
- W1963555901 cites W2032967937 @default.
- W1963555901 cites W2037968616 @default.
- W1963555901 cites W2056797133 @default.
- W1963555901 cites W2587415428 @default.
- W1963555901 doi "https://doi.org/10.1021/ja026199s" @default.
- W1963555901 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12236729" @default.
- W1963555901 hasPublicationYear "2002" @default.
- W1963555901 type Work @default.
- W1963555901 sameAs 1963555901 @default.
- W1963555901 citedByCount "20" @default.
- W1963555901 countsByYear W19635559012012 @default.
- W1963555901 countsByYear W19635559012013 @default.
- W1963555901 countsByYear W19635559012014 @default.
- W1963555901 countsByYear W19635559012021 @default.
- W1963555901 countsByYear W19635559012022 @default.
- W1963555901 crossrefType "journal-article" @default.
- W1963555901 hasAuthorship W1963555901A5013652065 @default.
- W1963555901 hasAuthorship W1963555901A5042708314 @default.
- W1963555901 hasAuthorship W1963555901A5071729996 @default.
- W1963555901 hasConcept C108204754 @default.
- W1963555901 hasConcept C112887158 @default.
- W1963555901 hasConcept C155647269 @default.
- W1963555901 hasConcept C161790260 @default.
- W1963555901 hasConcept C166950319 @default.
- W1963555901 hasConcept C178790620 @default.
- W1963555901 hasConcept C179104552 @default.
- W1963555901 hasConcept C181458950 @default.
- W1963555901 hasConcept C185592680 @default.
- W1963555901 hasConcept C2778176622 @default.
- W1963555901 hasConcept C2780051471 @default.
- W1963555901 hasConcept C32909587 @default.
- W1963555901 hasConcept C512968161 @default.
- W1963555901 hasConcept C71240020 @default.
- W1963555901 hasConcept C75079739 @default.
- W1963555901 hasConcept C75473681 @default.
- W1963555901 hasConceptScore W1963555901C108204754 @default.
- W1963555901 hasConceptScore W1963555901C112887158 @default.
- W1963555901 hasConceptScore W1963555901C155647269 @default.
- W1963555901 hasConceptScore W1963555901C161790260 @default.
- W1963555901 hasConceptScore W1963555901C166950319 @default.
- W1963555901 hasConceptScore W1963555901C178790620 @default.
- W1963555901 hasConceptScore W1963555901C179104552 @default.
- W1963555901 hasConceptScore W1963555901C181458950 @default.
- W1963555901 hasConceptScore W1963555901C185592680 @default.
- W1963555901 hasConceptScore W1963555901C2778176622 @default.
- W1963555901 hasConceptScore W1963555901C2780051471 @default.
- W1963555901 hasConceptScore W1963555901C32909587 @default.
- W1963555901 hasConceptScore W1963555901C512968161 @default.
- W1963555901 hasConceptScore W1963555901C71240020 @default.
- W1963555901 hasConceptScore W1963555901C75079739 @default.
- W1963555901 hasConceptScore W1963555901C75473681 @default.
- W1963555901 hasIssue "38" @default.
- W1963555901 hasLocation W19635559011 @default.
- W1963555901 hasLocation W19635559012 @default.
- W1963555901 hasOpenAccess W1963555901 @default.
- W1963555901 hasPrimaryLocation W19635559011 @default.
- W1963555901 hasRelatedWork W2033713882 @default.
- W1963555901 hasRelatedWork W2039946768 @default.
- W1963555901 hasRelatedWork W2057512467 @default.
- W1963555901 hasRelatedWork W2069921096 @default.
- W1963555901 hasRelatedWork W2112422553 @default.
- W1963555901 hasRelatedWork W2142401223 @default.
- W1963555901 hasRelatedWork W2345376172 @default.
- W1963555901 hasRelatedWork W2963982698 @default.
- W1963555901 hasRelatedWork W2970824832 @default.
- W1963555901 hasRelatedWork W4206217756 @default.
- W1963555901 hasVolume "124" @default.
- W1963555901 isParatext "false" @default.
- W1963555901 isRetracted "false" @default.
- W1963555901 magId "1963555901" @default.
- W1963555901 workType "article" @default.