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- W1963560997 abstract "The gas-solid reaction between methane and the lattice oxygen of Mi, Co, and Fe-oxides loaded on various support materials produced a synthesis gas (hydrogen and carbon monoxide) at 600-800°C. Metal oxides were reduced to metals or lower valence oxides, and they were re-oxidized to oxides by introducing air after the reaction. Thus, production of hydrogen or synthesis gas free from nitrogen can be achieved alternatively without using pure oxygen. As a metal oxide, Fe 2 O 3 and Rh 2 O 3 -loaded on Y 2 O 3 exhibited the highest H 2 selectivity of 60.1% with a moderate CH 4 conversion of 54% and a high lattice oxygen utilization of 84% at 800 °C." @default.
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- W1963560997 date "2008-11-01" @default.
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- W1963560997 title "Partial oxidation of CH4 with air to produce pure hydrogen and syngas" @default.
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- W1963560997 doi "https://doi.org/10.1016/j.cattod.2008.05.013" @default.
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