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• W1963567758 abstract "The 13C NMR spectra of some cyclopentadienylides including dimethyl-sulfoniumcyclopentadienylide (I), diphenylphosphoniumcyclopentadienylide (II), dimethylaminofulvene (III), diphenylfulvene (IV) and complexes of the ylides I and II with Group VI metal (Cr, Mo, W) carbonyls are studied. The shielding specificities of the carbon nuclei in the cyclopentadienyl rings of these systems are discussed. Coordination with the transition metal may balance essentially the electron density in the π-cyclopentadienylic fragments of the ylides along with the general enhancement of shielding of the carbon nuclei in these fragments. The degree of shielding depends on the nature of central metal atom varying in the sequence Cr > W > Mo." @default.
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• W1963567758 date "1977-04-01" @default.
• W1963567758 modified "2023-10-16" @default.
• W1963567758 title "The 13C NMR spectra of cyclopentadienylides and their complexes with the group vi metal carbonyls" @default.
• W1963567758 cites W1967863117 @default.
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• W1963567758 doi "https://doi.org/10.1016/s0022-328x(00)92135-1" @default.
• W1963567758 hasPublicationYear "1977" @default.
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