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- W1963568215 abstract "The microwave spectra of tertiarybutylphosphine (CH3)3CPH2, (CH3)3CPHD, and (CH3)3CPD2 have been recorded in the region 26.5–40.3 GHz. Both a- and c-type transitions were observed and assigned for the “light” and “heavy” molecules and a-type transitions were observed and assigned for the d1 species. The rigid rotor rotational constants were determined to be A = 4397.63 ± 0.04, B = 2878.88 ± 0.02, and C = 2870.86 ± 0.02 MHz for (CH3)3CPH2 and A= 4261.98 ± 0.04, B = 2769.82 ± 0.02, and C = 2752.71 ± 0.02 MHz for (CH3)3CPD2 and A = 4330 ± 2, B = 2831.45 ± 0.02, and C = 2801.50 ± 0.02 MHz for (CH3)3CPHD. Dipole moment components of |μa| = 1.06 ± 0.02, |μc| = 0.49 ± 0.02 and |μt| = 1.17 ± 0.02D were determined from the Stark effect. By assuming reasonable structural parameters for the tertiarybutyl and phosphine groups, a least-squares fit of the rotational constants gave λP-C = 1.896 Å and ∢CPH = 95.7°. No splitting was observed of the first excited state of the phosphine torsional mode." @default.
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- W1963568215 date "1978-04-01" @default.
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- W1963568215 title "Microwave spectrum of tertiary-butylphosphine" @default.
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- W1963568215 doi "https://doi.org/10.1016/0022-2852(78)90006-1" @default.
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