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• W1963582504 abstract "The anhydrous tri-iodides of plutonium, americium and curium under pressure have been investigated using absorption spectrophotometry. These initial studies on plutonium and curium tri-iodides together with the published data for americium tri-iodide show that the rhombohedral form of these compounds (BiI3-type structure) can be converted to the orthorhombic form (PuBr3-type structure) by applying pressure at room temperature. Absorption spectrophotometry can often differentiate between two crystallographic forms of a material and has been used in the present high-pressure studies to monitor the effects of pressure on the tri-iodides. A complication in these studies of the tri-iodides is a significant shift of their absorption edges with pressure from the near UV to the visible spectral region. With curium tri-iodide this shift causes interference with the major f-f absorption peaks and precludes identification by absorption spectrophotometry of the high pressure phase of CmI3." @default.
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• W1963582504 date "1987-06-01" @default.
• W1963582504 modified "2023-10-14" @default.
• W1963582504 title "Studies of selected transuranium and lanthanide tri-iodides under pressure using absorption spectrophotometry" @default.
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• W1963582504 doi "https://doi.org/10.1016/0022-5088(87)90470-x" @default.
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