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• W1963582624 abstract "3-Cyanocarbazoles, key-intermediates in the total synthesis of pyrido [4,3-b] carbazoles, have been obtained starting from easily available materials and involving the cyclization of diarylamines. The first step of the preparation consists in a SNAr reaction between a para substituted aniline and a chloro- (or bromo)-dinitrobenzene. This nucleophilic substitution has been found to be hindered by the steric effect of a methyl group, explained in terms of inhibition of resonance and confirmed by X-ray determination." @default.
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• W1963582624 date "1980-01-01" @default.
• W1963582624 modified "2023-09-25" @default.
• W1963582624 title "Acces aux dinitro-2,4 diarylamines par substitution nucleophile SNAr-limites de la reaction et application a la synthese de cyanocarbazoles" @default.
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• W1963582624 doi "https://doi.org/10.1016/0040-4020(80)88049-5" @default.
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