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• W1963584131 abstract "The solvent dependent photochemistry of fenofibric acid (FA) was studied by femtosecond transient absorption and nanosecond time-resolved resonance Raman experiments and density functional theory calculations. In acetonitrile-rich solution, a typical nπ* triplet state FA (3FA) is formed through a highly efficient intersystem crossing and then the 3FA species undergoes some reaction with water to generate a ketyl radical intermediate at low water concentrations. In contrast, nπ* 3FA changes from a reaction with water to generate a ketyl radical intermediate at lower water concentrations to a decarboxylation reaction with the assistance of water molecules to produce a biradical intermediate at higher water concentrations in water-rich solutions. The decarboxylation reaction leads to the formation of the FA carbanion in 50% phosphate buffer solution and the FA carbanion is observed on the picosecond to nanosecond time scale and the cleavage of the FA carbanion gives rise to the enolate 3− anion at later nanosecond delay times. As regards fenofibrate (FB), it only exhibits a benzophenone-like photochemistry, which consists of some reaction with water to generate a ketyl radical intermediate, being observed in the different aqueous solutions." @default.
• W1963584131 created "2016-06-24" @default.
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• W1963584131 date "2013-01-01" @default.
• W1963584131 modified "2023-10-17" @default.
• W1963584131 title "A time-resolved spectroscopy and density functional theory study of the solvent dependent photochemistry of fenofibric acid" @default.
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• W1963584131 doi "https://doi.org/10.1039/c2cp41739a" @default.
• W1963584131 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23238267" @default.
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