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- W1963585786 abstract "The acid-catalysed solvolysis of (R)-1-phenyl-1-methoxyethane was studied in mixtures of dilute aqueous perchloric acid and acetonitrile at 50°C. The rate of loss of optical activity (k α ) was found to be the same as the rate of solvolysis (k solv ) at both low and high water contents of the solvent. These results are not in accord with literature data on racemization and oxygen exchange of 1-phenylethanol in water, which has been discussed in terms of interconversion of chiral ion-dipole pair intermediates. The mechanistic implications of the results are discussed" @default.
- W1963585786 created "2016-06-24" @default.
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- W1963585786 date "1993-05-01" @default.
- W1963585786 modified "2023-10-11" @default.
- W1963585786 title "Acid-catalysed solvolysis of optically active 1-Phenyl-1-methoxythane. The role of ion- molecule pair intermediates" @default.
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- W1963585786 doi "https://doi.org/10.1002/poc.610060506" @default.
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