FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963588300> ?p ?o ?g. }

• W1963588300 endingPage "8781" @default.
• W1963588300 startingPage "8772" @default.
• W1963588300 abstract "Nanoporous materials with inherently tunable surface chemistries are poised to have a considerable impact in catalysis, separations, and nanopatterning. Using core−shell cylinder forming polystyrene-b-polyisoprene-b-polylactide (PS−PI−PLA) triblock terpolymers as templates, we were able to prepare aligned PI-coated nanoporous PS monoliths via the degradative removal of the cylindrical PLA cores. PS−PI−PLA precursors were synthesized using a combination of anionic (PS, PI) and ring-opening (PLA) polymerizations. The degree of order, alignment, and PLA degradation achievable was a strong function of molecular weight at a given triblock terpolymer composition. For intermediate molecular weight samples (25−28 kg mol-1), greater than 95% of the PLA was hydrolyzed through exposure of the monolith to a 0.1 wt % sodium dodecyl sulfate (SDS) solution in 0.5 N NaOH. However, low (17.5 kg mol-1) and high (46.8 kg mol-1) molecular weight samples of identical composition showed considerable resistance to PLA degradation. Treatment of the degraded monoliths with m-chloroperoxybenzoic acid in aqueous tert-butyl alcohol solutions permitted the controlled epoxidation of up to 75−80% of the PI alkene units. Despite some loss in pore alignment, scanning electron microscopy and small-angle X-ray scattering verified the retainment of the nanoporous structure following epoxidation." @default.
• W1963588300 created "2016-06-24" @default.
• W1963588300 creator A5016702200 @default.
• W1963588300 creator A5044358227 @default.
• W1963588300 creator A5086988569 @default.
• W1963588300 date "2006-11-15" @default.
• W1963588300 modified "2023-09-26" @default.
• W1963588300 title "Routes to Alkene and Epoxide Functionalized Nanoporous Materials from Poly(styrene-<i>b</i>-isoprene-<i>b</i>-lactide) Triblock Copolymers" @default.
• W1963588300 cites W1981015550 @default.
• W1963588300 cites W2000466466 @default.
• W1963588300 cites W2007333505 @default.
• W1963588300 cites W2016291808 @default.
• W1963588300 cites W2022373667 @default.
• W1963588300 cites W2026132129 @default.
• W1963588300 cites W2033247796 @default.
• W1963588300 cites W2041127332 @default.
• W1963588300 cites W2041596313 @default.
• W1963588300 cites W2042195344 @default.
• W1963588300 cites W2042675095 @default.
• W1963588300 cites W2061197908 @default.
• W1963588300 cites W2061798607 @default.
• W1963588300 cites W2064652168 @default.
• W1963588300 cites W2067631894 @default.
• W1963588300 cites W2074475195 @default.
• W1963588300 cites W2085554061 @default.
• W1963588300 cites W2103637866 @default.
• W1963588300 cites W2106756509 @default.
• W1963588300 cites W2111775077 @default.
• W1963588300 cites W2122719482 @default.
• W1963588300 cites W2949662930 @default.
• W1963588300 doi "https://doi.org/10.1021/ma061892b" @default.
• W1963588300 hasPublicationYear "2006" @default.
• W1963588300 type Work @default.
• W1963588300 sameAs 1963588300 @default.
• W1963588300 citedByCount "65" @default.
• W1963588300 countsByYear W19635883002012 @default.
• W1963588300 countsByYear W19635883002013 @default.
• W1963588300 countsByYear W19635883002014 @default.
• W1963588300 countsByYear W19635883002015 @default.
• W1963588300 countsByYear W19635883002016 @default.
• W1963588300 countsByYear W19635883002017 @default.
• W1963588300 countsByYear W19635883002018 @default.
• W1963588300 countsByYear W19635883002020 @default.
• W1963588300 countsByYear W19635883002021 @default.
• W1963588300 countsByYear W19635883002022 @default.
• W1963588300 countsByYear W19635883002023 @default.
• W1963588300 crossrefType "journal-article" @default.
• W1963588300 hasAuthorship W1963588300A5016702200 @default.
• W1963588300 hasAuthorship W1963588300A5044358227 @default.
• W1963588300 hasAuthorship W1963588300A5086988569 @default.
• W1963588300 hasConcept C152815550 @default.
• W1963588300 hasConcept C15920480 @default.
• W1963588300 hasConcept C159985019 @default.
• W1963588300 hasConcept C161790260 @default.
• W1963588300 hasConcept C171250308 @default.
• W1963588300 hasConcept C178790620 @default.
• W1963588300 hasConcept C184651966 @default.
• W1963588300 hasConcept C185592680 @default.
• W1963588300 hasConcept C188027245 @default.
• W1963588300 hasConcept C192562407 @default.
• W1963588300 hasConcept C2776254738 @default.
• W1963588300 hasConcept C2776743539 @default.
• W1963588300 hasConcept C2776920199 @default.
• W1963588300 hasConcept C2777566558 @default.
• W1963588300 hasConcept C2777922577 @default.
• W1963588300 hasConcept C2780959689 @default.
• W1963588300 hasConcept C48940184 @default.
• W1963588300 hasConcept C521977710 @default.
• W1963588300 hasConceptScore W1963588300C152815550 @default.
• W1963588300 hasConceptScore W1963588300C15920480 @default.
• W1963588300 hasConceptScore W1963588300C159985019 @default.
• W1963588300 hasConceptScore W1963588300C161790260 @default.
• W1963588300 hasConceptScore W1963588300C171250308 @default.
• W1963588300 hasConceptScore W1963588300C178790620 @default.
• W1963588300 hasConceptScore W1963588300C184651966 @default.
• W1963588300 hasConceptScore W1963588300C185592680 @default.
• W1963588300 hasConceptScore W1963588300C188027245 @default.
• W1963588300 hasConceptScore W1963588300C192562407 @default.
• W1963588300 hasConceptScore W1963588300C2776254738 @default.
• W1963588300 hasConceptScore W1963588300C2776743539 @default.
• W1963588300 hasConceptScore W1963588300C2776920199 @default.
• W1963588300 hasConceptScore W1963588300C2777566558 @default.
• W1963588300 hasConceptScore W1963588300C2777922577 @default.
• W1963588300 hasConceptScore W1963588300C2780959689 @default.
• W1963588300 hasConceptScore W1963588300C48940184 @default.
• W1963588300 hasConceptScore W1963588300C521977710 @default.
• W1963588300 hasIssue "25" @default.
• W1963588300 hasLocation W19635883001 @default.
• W1963588300 hasOpenAccess W1963588300 @default.
• W1963588300 hasPrimaryLocation W19635883001 @default.
• W1963588300 hasRelatedWork W1963588300 @default.
• W1963588300 hasRelatedWork W1981969617 @default.
• W1963588300 hasRelatedWork W1990341081 @default.
• W1963588300 hasRelatedWork W2009697282 @default.
• W1963588300 hasRelatedWork W2011909547 @default.
• W1963588300 hasRelatedWork W2037434603 @default.
• W1963588300 hasRelatedWork W2081528498 @default.
• W1963588300 hasRelatedWork W2168456778 @default.

• next