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- W1963608847 abstract "We propose a model for the Fe atomic displacements in the low-temperature phase of magnetite $({text{Fe}}_{3}{text{O}}_{4})$, based on the analysis of the photon energy dependence of the scattered intensity of selected reflections in a resonant x-ray scattering experiment. The symmetry of the displacement pattern is forced to be consistent with the $Cc$ space group, long time claimed to be the actual symmetry of the low-temperature phase. Fe positions at octahedral sites and the corresponding charges are accounted for by a fitting procedure comparing simulations and experiment. We found a pattern of small distortions in the $atext{ensuremath{-}}b$ plane. An independent sensitivity to the charge occupancy permits to refine the model of charge ordering previously proposed. Finally we have computed the electric moment of the combined charge displacements to be $1.5text{ }ensuremath{mu}text{C}/{text{cm}}^{2}$." @default.
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- W1963608847 date "2008-10-29" @default.
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- W1963608847 title "Low-temperature structure of magnetite studied using resonant x-ray scattering" @default.
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- W1963608847 doi "https://doi.org/10.1103/physrevb.78.134110" @default.
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