Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963609834> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W1963609834 endingPage "91" @default.
- W1963609834 startingPage "83" @default.
- W1963609834 abstract "Abstract Slow diffusion of cobalt chloride with Na2[Fe(CN)5NO]-5H2O in aqueous solution produced crystals of Co[Fe(CN)5NO]-5H2O suitable for analysis by three-dimensional, single-crystal X-ray diffractometry. This polynuclear transition metal cyanide crystallized in the cubic space group Fm3m (No. 225, O5 h), a = 10.28 I (2)Å, with three formula units per cell. D m = 1.67(1) Mg m−3 and D x = 1.673 Mg m−3. Final full-matrix least-squares refinement of 102 unique reflections converged to R = 0.020 and R w = 0.019. The iron nucleus is octahedrally coordinated to five cyanide ligands and a nitrosyl group and the cobalt nucleus is octahedrally coordinated to five cyanide ligands and one water molecule. Cyanide bridging (Fe-C≡N-Co) links the metal centers, providing a cubic framework within which uncoordinated water molecules occupy three crystallographically distinct environments. These uncoordinated water molecules are held in position by hydrogen bonding and/or van der Waals forces. The crystal lattice of cobalt nitroprusside is characterized by unique vacancies and a high degree of disorder, which can be described as a super-positioning of various ordered unit cells. Infrared, thermogravimetric and crystallographic data have led to the formulation of a plausible model for cubic nitroprussides." @default.
- W1963609834 created "2016-06-24" @default.
- W1963609834 creator A5002574622 @default.
- W1963609834 creator A5002963809 @default.
- W1963609834 creator A5062888913 @default.
- W1963609834 date "1991-07-01" @default.
- W1963609834 modified "2023-10-03" @default.
- W1963609834 title "Synthesis, Spectroscopic Studies and X-Ray Crystal Structure Analysis of Cobalt Nitroprusside, Co[Fe(CN)<sub>5</sub>NO]·5H<sub>2</sub>O" @default.
- W1963609834 cites W1968333212 @default.
- W1963609834 cites W1986164181 @default.
- W1963609834 cites W1992661660 @default.
- W1963609834 cites W1997427834 @default.
- W1963609834 cites W1999736898 @default.
- W1963609834 cites W2006208949 @default.
- W1963609834 cites W2029806469 @default.
- W1963609834 cites W2052165872 @default.
- W1963609834 cites W2053841107 @default.
- W1963609834 cites W2056153768 @default.
- W1963609834 cites W2062824148 @default.
- W1963609834 cites W2067259222 @default.
- W1963609834 cites W2071187551 @default.
- W1963609834 cites W2077760837 @default.
- W1963609834 cites W2084108160 @default.
- W1963609834 cites W2112240997 @default.
- W1963609834 cites W2326133559 @default.
- W1963609834 cites W2332712130 @default.
- W1963609834 cites W2950870047 @default.
- W1963609834 cites W2952924781 @default.
- W1963609834 cites W3139174741 @default.
- W1963609834 doi "https://doi.org/10.1080/00958979109409738" @default.
- W1963609834 hasPublicationYear "1991" @default.
- W1963609834 type Work @default.
- W1963609834 sameAs 1963609834 @default.
- W1963609834 citedByCount "37" @default.
- W1963609834 countsByYear W19636098342013 @default.
- W1963609834 countsByYear W19636098342015 @default.
- W1963609834 countsByYear W19636098342016 @default.
- W1963609834 countsByYear W19636098342018 @default.
- W1963609834 countsByYear W19636098342019 @default.
- W1963609834 countsByYear W19636098342020 @default.
- W1963609834 countsByYear W19636098342021 @default.
- W1963609834 countsByYear W19636098342022 @default.
- W1963609834 countsByYear W19636098342023 @default.
- W1963609834 crossrefType "journal-article" @default.
- W1963609834 hasAuthorship W1963609834A5002574622 @default.
- W1963609834 hasAuthorship W1963609834A5002963809 @default.
- W1963609834 hasAuthorship W1963609834A5062888913 @default.
- W1963609834 hasConcept C112887158 @default.
- W1963609834 hasConcept C115624301 @default.
- W1963609834 hasConcept C126061179 @default.
- W1963609834 hasConcept C147789679 @default.
- W1963609834 hasConcept C153642686 @default.
- W1963609834 hasConcept C178790620 @default.
- W1963609834 hasConcept C179104552 @default.
- W1963609834 hasConcept C184651966 @default.
- W1963609834 hasConcept C185592680 @default.
- W1963609834 hasConcept C2778455166 @default.
- W1963609834 hasConcept C32909587 @default.
- W1963609834 hasConcept C515602321 @default.
- W1963609834 hasConcept C544153396 @default.
- W1963609834 hasConcept C73922627 @default.
- W1963609834 hasConcept C8010536 @default.
- W1963609834 hasConceptScore W1963609834C112887158 @default.
- W1963609834 hasConceptScore W1963609834C115624301 @default.
- W1963609834 hasConceptScore W1963609834C126061179 @default.
- W1963609834 hasConceptScore W1963609834C147789679 @default.
- W1963609834 hasConceptScore W1963609834C153642686 @default.
- W1963609834 hasConceptScore W1963609834C178790620 @default.
- W1963609834 hasConceptScore W1963609834C179104552 @default.
- W1963609834 hasConceptScore W1963609834C184651966 @default.
- W1963609834 hasConceptScore W1963609834C185592680 @default.
- W1963609834 hasConceptScore W1963609834C2778455166 @default.
- W1963609834 hasConceptScore W1963609834C32909587 @default.
- W1963609834 hasConceptScore W1963609834C515602321 @default.
- W1963609834 hasConceptScore W1963609834C544153396 @default.
- W1963609834 hasConceptScore W1963609834C73922627 @default.
- W1963609834 hasConceptScore W1963609834C8010536 @default.
- W1963609834 hasIssue "1" @default.
- W1963609834 hasLocation W19636098341 @default.
- W1963609834 hasOpenAccess W1963609834 @default.
- W1963609834 hasPrimaryLocation W19636098341 @default.
- W1963609834 hasRelatedWork W1991883810 @default.
- W1963609834 hasRelatedWork W2028104741 @default.
- W1963609834 hasRelatedWork W2031538813 @default.
- W1963609834 hasRelatedWork W2040223897 @default.
- W1963609834 hasRelatedWork W2066405456 @default.
- W1963609834 hasRelatedWork W2067967944 @default.
- W1963609834 hasRelatedWork W2072417293 @default.
- W1963609834 hasRelatedWork W2109919885 @default.
- W1963609834 hasRelatedWork W2788975530 @default.
- W1963609834 hasRelatedWork W646380683 @default.
- W1963609834 hasVolume "24" @default.
- W1963609834 isParatext "false" @default.
- W1963609834 isRetracted "false" @default.
- W1963609834 magId "1963609834" @default.
- W1963609834 workType "article" @default.