Matches in SemOpenAlex for { <https://semopenalex.org/work/W1963624069> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W1963624069 endingPage "263" @default.
- W1963624069 startingPage "251" @default.
- W1963624069 abstract "An investigation of the reactions of some perfluoroaromatic compounds with organomagnesium compounds has been made. It was found that the expected substitution products arising from simple nucleophilic reaction between a perfluoroaromatic and an organomagnesium compounds are not the only products formed during these reactions. The anomalous products formed apparently resulted from an intermediate metallation reaction. Decafluorobiphenyl (x moles) when allowed to react with ethylmagnesium bromide (4x moles) afforded the expected 4-ethylnonafluorobiphenyl and 4,4′-diethyloctafluorobiphenyl and the anomalous 4-hydrononafluorobiphenyl, 4,4′-dihydrooctafluorobiphenyl and 4-ethyl-4′-H-octafluorobiphenyl. It has been shown that the intermediate organomagnesium compounds formed can be derivatized with trimethylchlorosilane to yield perfluoroaryltrimethylsilanes. The effect of changing stoichiometry of reactants on product distribution is discussed." @default.
- W1963624069 created "2016-06-24" @default.
- W1963624069 creator A5030451066 @default.
- W1963624069 creator A5039962972 @default.
- W1963624069 date "1970-04-01" @default.
- W1963624069 modified "2023-09-27" @default.
- W1963624069 title "Anomalous reactions of organomagnesium reagents with perfluoroaromatic compounds" @default.
- W1963624069 cites W1996043297 @default.
- W1963624069 cites W2010456702 @default.
- W1963624069 cites W2019478224 @default.
- W1963624069 cites W2043557630 @default.
- W1963624069 cites W2055678516 @default.
- W1963624069 cites W2072630789 @default.
- W1963624069 cites W2084686933 @default.
- W1963624069 cites W2091270994 @default.
- W1963624069 cites W2155588898 @default.
- W1963624069 cites W2318400521 @default.
- W1963624069 cites W2330109294 @default.
- W1963624069 cites W2333033091 @default.
- W1963624069 doi "https://doi.org/10.1016/s0022-328x(00)86040-4" @default.
- W1963624069 hasPublicationYear "1970" @default.
- W1963624069 type Work @default.
- W1963624069 sameAs 1963624069 @default.
- W1963624069 citedByCount "12" @default.
- W1963624069 countsByYear W19636240692016 @default.
- W1963624069 countsByYear W19636240692017 @default.
- W1963624069 countsByYear W19636240692020 @default.
- W1963624069 countsByYear W19636240692021 @default.
- W1963624069 countsByYear W19636240692023 @default.
- W1963624069 crossrefType "journal-article" @default.
- W1963624069 hasAuthorship W1963624069A5030451066 @default.
- W1963624069 hasAuthorship W1963624069A5039962972 @default.
- W1963624069 hasConcept C111185830 @default.
- W1963624069 hasConcept C134121241 @default.
- W1963624069 hasConcept C135731615 @default.
- W1963624069 hasConcept C144082473 @default.
- W1963624069 hasConcept C155647269 @default.
- W1963624069 hasConcept C161790260 @default.
- W1963624069 hasConcept C17112743 @default.
- W1963624069 hasConcept C178790620 @default.
- W1963624069 hasConcept C178907741 @default.
- W1963624069 hasConcept C185592680 @default.
- W1963624069 hasConcept C191897082 @default.
- W1963624069 hasConcept C192562407 @default.
- W1963624069 hasConcept C2776300020 @default.
- W1963624069 hasConcept C40875361 @default.
- W1963624069 hasConceptScore W1963624069C111185830 @default.
- W1963624069 hasConceptScore W1963624069C134121241 @default.
- W1963624069 hasConceptScore W1963624069C135731615 @default.
- W1963624069 hasConceptScore W1963624069C144082473 @default.
- W1963624069 hasConceptScore W1963624069C155647269 @default.
- W1963624069 hasConceptScore W1963624069C161790260 @default.
- W1963624069 hasConceptScore W1963624069C17112743 @default.
- W1963624069 hasConceptScore W1963624069C178790620 @default.
- W1963624069 hasConceptScore W1963624069C178907741 @default.
- W1963624069 hasConceptScore W1963624069C185592680 @default.
- W1963624069 hasConceptScore W1963624069C191897082 @default.
- W1963624069 hasConceptScore W1963624069C192562407 @default.
- W1963624069 hasConceptScore W1963624069C2776300020 @default.
- W1963624069 hasConceptScore W1963624069C40875361 @default.
- W1963624069 hasIssue "2" @default.
- W1963624069 hasLocation W19636240691 @default.
- W1963624069 hasOpenAccess W1963624069 @default.
- W1963624069 hasPrimaryLocation W19636240691 @default.
- W1963624069 hasRelatedWork W1540666866 @default.
- W1963624069 hasRelatedWork W2081542712 @default.
- W1963624069 hasRelatedWork W2086068589 @default.
- W1963624069 hasRelatedWork W2097014657 @default.
- W1963624069 hasRelatedWork W2139748406 @default.
- W1963624069 hasRelatedWork W2156700048 @default.
- W1963624069 hasRelatedWork W2949229842 @default.
- W1963624069 hasRelatedWork W2950203061 @default.
- W1963624069 hasRelatedWork W2950474205 @default.
- W1963624069 hasRelatedWork W3164849189 @default.
- W1963624069 hasVolume "22" @default.
- W1963624069 isParatext "false" @default.
- W1963624069 isRetracted "false" @default.
- W1963624069 magId "1963624069" @default.
- W1963624069 workType "article" @default.