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- W1963661438 abstract "Abstract OH formation from the ozonolysis reactions of seven internal alkenes with 4–6 carbons, styrene, trans - β -methyl styrene, and α -methyl styrene was studied using complementary techniques. A small-ratio relative-rate technique in which small quantities of OH tracers are added to monitor OH formation yields provided the following results: trans -2-butene, 0.64±0.12; cis -2-butene, 0.33±0.05; trans -2-pentene, 0.46±0.08; cis -2-pentene, 0.29±0.06; trans -3-hexene, 0.53±0.08; cis -3-hexene, 0.36±0.07; and 2-methyl-2-butene, 0.98±0.24. For styrene, trans - β -methyl styrene, and α -methyl styrene, OH yields of 0.07±0.04, 0.22±0.09, and 0.23±0.12 were measured, respectively. A second method, which monitors product formation from the OH reaction with 2-butanol was used to derive OH formation yields from 2,3-dimethyl-2-butene, 2-methyl-2-butene and cis -2-pentene, and provided yields of 0.91±0.14, 0.80±0.12, and 0.27±0.07, respectively. The results are briefly discussed in terms of the relationship between structures of these alkenes and OH formation." @default.
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- W1963661438 date "2002-01-01" @default.
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- W1963661438 title "Production of OH radicals from the reactions of C4–C6 internal alkenes and styrenes with ozone in the gas phase" @default.
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- W1963661438 doi "https://doi.org/10.1016/s1352-2310(01)00445-9" @default.
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