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- W1963667588 abstract "Abstract The trigonal distortions of Ni2+, V2+, Mn2+ and Co2+ ions in ZnSiF6 · 6H2O crystal have been studied by analysing their zero-field splittings and the anisotropy of g factor (characterized by Δg = g ⊥ − g ∥). From the studies, it is found that the sign of trigonal distortion (compression or elongation) of octahedral environment of impurity ion is impurity-dependent, i.e., when the ionic radius of impurity is greater than that of the replaced Zn2+ ion, the octahedral environment of impurity is compressed, whereas if the ionic radius of impurity is smaller than that of Zn2+, it is elongated. This point is similar to the case of isomorphous pure crystal where the paramagnetic ion is the host ion rather than the impurity." @default.
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- W1963667588 date "1997-03-01" @default.
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- W1963667588 title "Local trigonal distortions of some paramagnetic impurity centers in ZnSiF6· 6H2O crystal" @default.
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- W1963667588 doi "https://doi.org/10.1080/10420159708216857" @default.
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