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• W1963669202 abstract "Results for pyridine (Py) adsorption on columnar-structured (cs) gold substrates from acid solutions at different potentials and 298 K are compared to the predictions of a recently proposed Langmuirian adsorption model at columnar surfaces. The difference in the apparent adsorption Gibbs energy derived from the adsorption isotherm of Py on cs- and smooth gold substrates was accounted for by a correction factor (f) that depends on the roughness (R) of the substrate according to f∝R−n, as expected from Monte Carlo simulation of the model. This agreement indicates that the substrate geometry plays a key role in the interpretation of adsorption isotherms." @default.
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• W1963669202 date "1999-09-01" @default.
• W1963669202 modified "2023-10-14" @default.
• W1963669202 title "Steric effects on molecular adsorption at columnar surfaces. A model for the adsorption of pyridine on gold electrodes" @default.
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• W1963669202 doi "https://doi.org/10.1016/s0022-0728(99)00308-3" @default.
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